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NTA Abhyas 2020
Exam
NTA Abhyas
Year
2020
Subject
Chemistry
Chapter
Chemical Equilibrium

NTA Abhyas 2020 · Chemistry · Chemical Equilibrium

Initially, 0.8 mol of PC l _ 5 and 0.2 mol of PC l _ 3 are mixed in...

Initially, 0.8 mol of PCl5PC{l}_{5} and 0.2 mol of PCl3PC{l}_{3} are mixed in a one litre vessel. At equilibrium, 0.4 mol of PCl3PC{l}_{3} is present. The value of Kc{K}_{c} for the reaction, PCl5PC{l}_{5}\left(g\right) ⇌ PC{l}_{3}(g)+Cl2(g),\left(g\right) + C{l}_{2}\left(g\right), would beInitially, 0.8 mol of PC l _ 5 and 0.2 mol of PC l _ 3 are mixed in a one litre vessel. At equilibrium, 0.4 mol of PC l

Options

  1. A0.13\text{mol}{\textL^{- 1}
  2. B0.66\text{mol}{\textL^{- 1}
  3. C0.013\text{mol}{\textL^{- 1}
  4. D0.05\text{mol}{\textL^{- 1}

Correct answer

A. 0.13\text{mol}{\textL^{- 1}

Step-by-step solution

Initially, 0.8 mol of PC l _ 5 and 0.2 mol of PC l _ 3 are mixed in a one litre vessel. At equilibrium, 0.4 mol of PC l

So x=0.2x = 0.2

Kc=[PCl3][Cl2][PCl5]=0.4×0.20.6{K}_{c} = \dfrac{\left[PC{l}_{3}\right]\left[C{l}_{2}\right]}{\left[PC{l}_{5}\right]} = \dfrac{0.4 \times 0.2}{0.6}

= 0.13\text{mol}{\textL^{- 1}
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