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NTA Abhyas JEE Main2020ChemistryGeneral Organic ChemistryPractice

Among the following compounds the most acidic is

Options

  1. AP- hydroxybenzoic acid
  2. BP- nitrophenol
  3. CP- toluic acid
  4. DO- hydroxybenzoic acid

Correct answer

D. O- hydroxybenzoic acid

Step-by-step solution

Acidic nature ∝ electron withdrawing group - I , - R , ortho effect Acidic nature ∝ 1 e l e c t r o n r e l e a s i n g g r o u p + I , + R A carboxylic acid is more acidic than phenol due to more stability of conjugate base. Due to ortho effect o- hydroxyl benzoic acid is strongest acid here and correct order of decreasing of acidic nature is

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