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NTA Abhyas JEE Main2020Chemistryp Block Elements (Group 15, 16, 17 & 18)Practice

A red coloured mixed oxide ( X ) on treatment with conc. H N O 3 gives a compound Y . ( Y ) with HCl produces a chloride ( Z ) which is insoluble in cold water but soluble in hot water, ( Z ) can also be formed by treating ( X ) with conc. H C l . Compounds ( X ) , ( Y ) and ( Z ) are:

Options

  1. APb 3 O 4 , PbNO 3 , PbCl 2
  2. BM n 3 O 4 , M n O 2 , M n C l 2
  3. CF e 3 O 4 , F e 2 O 3 , F e C l 3
  4. DF e 3 O 4 , F e O , F e C l 2

Correct answer

A. Pb 3 O 4 , PbNO 3 , PbCl 2

Step-by-step solution

P b 3 O 4 X is red coloured mixed oxideof P b O and P b O 2 . Pb 3 O 4 X +4HNO 3 → Pb NO 3 2 Y +PbO 2 +2H 2 O Pb NO 3 2 + 2HCl dil → PbCl 2 Z +2HNO 3 P b C l 2 in insoluble in cold water but soluble in hot. P b 3 O 4 ( X ) + 8 H C l → 3 P b C l 2 + 4 H 2 O + C l 2

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