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Calculate Δ H f o for chloride ion from the following data: 1 2 H 2 g + 1 2 Cl 2 g → HCl g ; ΔH f o = − 92.4 kJ HCl g + nH 2 O → H + aq + Cl − aq ; ΔH f o = − 74.8 kJ ΔΗ f o of H + aq = 0.0 kJ

Options

  1. A- 167.2 k J
  2. B- 165.2 k J
  3. C- 157.2 k J
  4. D- 147.2 k J

Correct answer

A. - 167.2 k J

Step-by-step solution

Given, 1 2 H 2 g + aq → H + aq + e − ; ΔH o = 0 … . i 1 2 H 2 g + 1 2 Cl 2 g → HCl g ; ΔH o = − 92.4 kJ … ii HCl g + nH 2 O l →  H + aq   + Cl − aq   ; ΔH o =   − 74.8  kJ … iii HCl g + nH 2 O l →  H + aq   + Cl − aq   ; ΔH o =   − 74.8  kJ … iii i i + i i i − i ∴ 1 2 Cl 2 g + aq + e − → Cl − aq ; ΔH = − 92.4 − 74.8 kJ − 167.2 kJ … . iv Heat of formation for Cl − aq = − 167.2 k

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