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NTA Abhyas NEET2020ChemistryChemical Bonding and Molecular StructurePractice

Which statement is NOT correct? (According to Valence bond theory)

Options

  1. AA sigma(σ) bond is weaker than a π - b o n d
  2. BA sigma bond is stronger than a π - b o n d
  3. CA double bond is stronger than a single bond
  4. DA double bond is shorter than a single bond

Correct answer

A. A sigma(σ) bond is weaker than a π - b o n d

Step-by-step solution

A σ - bond is stronger than a π - bond. Sigma σ bonds are formed by head on overlap of unhybridised s - s , p - p o r s - p orbitals and hybridized orbitals s p , s p 2 , s p 3 , s p 3 d a n d s p 3 d 2 . Hence, σ bond are strong bonds. Where as Pi π - bonds are formed by side ways overlap of unhybridised p and d orbitals. Hence π bonds are weak bonds.

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