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NTA Abhyas NEET2020Chemistryp Block Elements (Group 15, 16, 17 & 18)Practice

In Lassaigne’s test for the detection of halogens, the sodium fusion extract is first boiled with concentrated nitric acid. This is

Options

  1. ATo dissolve A g 2 S
  2. BTo remove silver halides
  3. CTo decompose N a 2 S and NaCN, if present
  4. DBecause A g 2 S and AgCN are insoluble in nitric acid

Correct answer

C. To decompose N a 2 S and NaCN, if present

Step-by-step solution

For the test of halogens, it is necessary to remove sodium cyanide and sodium sulphide from the sodium extract if N and S are present. It is possible by boiling sodium extract with cocn. H N O 3 as follows N a C N + H N O 3 → N a N O 3 + H C N ↑ N a 2 S + 2 H N O 3 → 2 N a N O 3 + H 2 S ↑

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