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NEETChemistryCoordination Compounds

Among the statements a - d , the incorrect ones are: a Octahedral C o I I I complexes with strong field ligands have very high magnetic moments b When ∆ 0 < P , the d-electron configuration of C o I I I in an octahedral complex is t e g 4 e g 2 c Wavelength of light absorbed by C o e n 3 3 + is lower than that of C o F 6 3 - d If the ∆ 0 for an octahedral complex of C o I I I is 18,000 c m - 1 , the ∆ t for its tetra

Options

  1. Aa and d only
  2. Bc and d only
  3. Ca and b only
  4. Db and c only

Correct answer

A. a and d only

Step-by-step solution

So if there are strong field ligands in complex, pairing of electrons will take place, due to which number of unpaired electrons decrease due to which magnetic moment decrease. ( c ) Splitting power of ethylenediamine (en) is greater than fluoride F − ligand therefore more energy absorbed by Co en 3 + as compared to CoF 6 3 − So wave length of light absorbed by Co en 3 + is lower than that of CoF 6 3 − (d) Δ t = 4 9 Δ 0 so if Δ 0 = 18 , 000 cm − 1 Δ t = 4 9 × 18000 = 8000 cm − 1 Statement ( a ) and ( d ) are incorr

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