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NEETChemistryCoordination Compounds

Match List-I with List-II. Choose the correct answer from the options given below:

Options

  1. AA-II, B-IV, C-I, D-III
  2. BA-IV, B-I, C-III, D-II
  3. CA-IV, B-I, C-II, D-III
  4. DA-II, B-IV, C-III, D-I

Correct answer

C. A-IV, B-I, C-II, D-III

Step-by-step solution

d-orbital is degenerate which split into two levels e g and t 2 g in the presence of ligands. This splitting is due to the presence of ligands. This is called the crystal-field splitting and the energy difference between the two levels is called the crystal-field splitting energy, Δ 0 . (A) Ti 2 + : 4 s 0 3 d 2 t 2 g e – = 2 e g e – = 0 Δ 0 = 2 - . 4 Δ 0 = - . 8 Δ 0 (B) V 2 + : 4 s 0 3 d 3 t 2 g e – = 3 e g e – = 0 Δ 0 = 3 - . 4 Δ 0 = - 1 . 2 Δ 0 (C) Mn 3 + = 4 s 0 3 d 4 t 2 g e – = 3 e g e – = 1 Δ 0 = 3 - . 4 Δ 0

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