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NEETChemistryCoordination Compounds

Match List I with List II List I Coordination entity List II Wavelength of light absorbed in nm A CoCl NH 3 5 2 + I. 310 B Co NH 3 6 3 + II. 475 C Co ( CN ) 6 3 - III. 535 D Cu H 2 O 4 2 + IV. 600 Choose the correct answer from the options given below :-

Options

  1. AA - IV , B - I , C - III , D - II
  2. BA - III , B - II , C - I , D - IV
  3. CA - III , B - I , C - II , D - IV
  4. DA - II , B - III , C - IV , D - I

Correct answer

B. A - III , B - II , C - I , D - IV

Step-by-step solution

Co-ordination compounds absorb a particular wavelength following certain rules. Wavelength of light absorbed ∝ 1 Oxidation state of metal ion ∝ 1 Strength of ligand Ligand field strength - CN - > NH 3 > H 2 O > Cl - List I Coordination entity List II Wavelength of light absorbed in nm A CoCl NH 3 5 2 + I. 535 B Co NH 3 6 3 + II. 475 C Co ( CN ) 6 3 - III. 310 D Cu H 2 O 4 2 + IV. 600

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