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NEETChemistryCoordination Compounds

Ethane-1,2-diamine (en) is an example of a/an:

Options

  1. Amonodentate ligand with a nitrogen donor atom
  2. Bbidentate ligand with one nitrogen and one oxygen donor atom
  3. Cbidentate ligand with two nitrogen donor atoms
  4. Dambidentate ligand

Correct answer

C. bidentate ligand with two nitrogen donor atoms

Step-by-step solution

Ethane-1,2-diamine (H₂ N-CH₂ -CH₂ -NH₂ ) contains two nitrogen atoms, each possessing a lone pair of electrons. It can coordinate to a central metal ion through both of these nitrogen atoms simultaneously, making it a bidentate (or didentate) ligand. It is not an ambidentate ligand because it does not have two different types of donor atoms to choose from, and it is not a monodentate ligand because it binds through two sites. Answer: bidentate ligand with two nitrogen donor atoms

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