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NEETChemistryCoordination Compounds

Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): The EDTA ⁴⁻ ion binds through two nitrogen and four oxygen donor atoms to a central metal ion. Reason (R): EDTA ⁴⁻ is a hexadentate ligand. In the light of the above statements, choose the most appropriate answer from the options given below:

Options

  1. ABoth Assertion and Reason are correct and Reason is the correct explanation for Assertion.
  2. BBoth Assertion and Reason are correct but Reason is not the correct explanation for Assertion.
  3. CAssertion is correct but Reason is incorrect.
  4. DAssertion is incorrect but Reason is correct.

Correct answer

B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion.

Step-by-step solution

Assertion (A) is correct because the structure of the ethylenediaminetetraacetate (EDTA ⁴⁻ ) ion contains two nitrogen atoms and four oxygen atoms (from four acetate groups) that act as donor sites. Reason (R) is also correct because a ligand that binds through six donor atoms is termed a hexadentate ligand. However, Reason (R) is not the correct explanation for Assertion (A). The classification of the ligand as hexadentate is a consequence of its structure, but the term 'hexadentate' itself does not explain why th

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