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NEETChemistryCoordination Compounds

Given below are four statements regarding coordination compounds: (I) The complex [ Co ( NH ₃)₄ Cl ₂]^+ exhibits both geometrical and optical isomerism. (II) Facial (fac) and meridional (mer) isomers are shown by octahedral complexes of type MA ₃ B ₃ . (III) The complex [ Pt ( en )₂]²⁺ is optically active. (IV) Linkage isomerism arises in coordination compounds containing ambidentate ligands. How many of the above st

Options

  1. AOnly one
  2. BOnly two
  3. COnly three
  4. DAll four

Correct answer

B. Only two

Step-by-step solution

Statement (I) is incorrect: The complex [ Co ( NH ₃)₄ Cl ₂]^+ is an octahedral complex of type MA ₄ B ₂ . It exhibits geometrical isomerism (cis and trans forms), but both forms possess a plane of symmetry and are optically inactive. Statement (II) is correct: Octahedral complexes of the type MA ₃ B ₃ (e.g., [ Co ( NH ₃)₃( NO ₂)₃] ) exhibit facial (fac) and meridional (mer) geometrical isomerism. Statement (III) is incorrect: Platinum(II) forms square planar complexes. The complex [ Pt ( en )₂]²⁺ has a square plana

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