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NEET2005ChemistryCoordination CompoundsActual

An aqueous solution of CoCl ₂ on addition of excess of concentrated HCl turns blue due to formation of

Options

  1. A[ Co ( H ₂ O ₄ Cl ₂ ] .
  2. B[ Co ( H ₂ O )₂ Cl ₄ ]²⁻
  3. C[ CoCl ₄ ]²⁻
  4. D[ Co ( H ₂ O ₂ Cl ₂ ] .

Correct answer

C. [ CoCl ₄ ]²⁻

Step-by-step solution

CoCl ₂ is a weak Lewis acid, reacting with chloride ion to produce salt containing the tetrahedral [ CoCl ₄ ]²⁻ ion. CoCl ₂ is blue when anhydrous, and a deep magenta colour when hydrated, for this reason it is widely used as an indicator for water.

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