NEET2005ChemistryCoordination CompoundsActual
An aqueous solution of CoCl ₂ on addition of excess of concentrated HCl turns blue due to formation of
Options
- A[ Co ( H ₂ O ₄ Cl ₂ ] .
- B[ Co ( H ₂ O )₂ Cl ₄ ]²⁻
- C[ CoCl ₄ ]²⁻
- D[ Co ( H ₂ O ₂ Cl ₂ ] .
Correct answer
C. [ CoCl ₄ ]²⁻
Step-by-step solution
CoCl ₂ is a weak Lewis acid, reacting with chloride ion to produce salt containing the tetrahedral [ CoCl ₄ ]²⁻ ion. CoCl ₂ is blue when anhydrous, and a deep magenta colour when hydrated, for this reason it is widely used as an indicator for water.