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NEET2008ChemistryCoordination CompoundsActual

Which does not give a precipitate with ( AgNO ₃ ) solution?

Options

  1. A( [ Co ( NH ₃ )₆ ] Cl ₃ )
  2. B( [ Co ( NH ₃ )₅ Cl ] Cl ₂ )
  3. C( [ Co ( NH ₃ )₄ Cl ₂ ] Cl )
  4. D( [ Co ( NH ₃ )₃ Cl ₃ ] )

Correct answer

D. ( [ Co ( NH ₃ )₃ Cl ₃ ] )

Step-by-step solution

( [ Co ( NH ₃ )₃ Cl ₃ ] ) does not give a precipitate with ( AgNO ₃ ) solution because in it all the chlorine atoms are attached by secondary valencies.

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