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JEE Advanced 2024Paper 2
Exam
JEE Advanced
Year
2024
Paper
Paper 2
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Advanced 2024 · Paper 2 · Chemistry · Alcohols Phenols and Ethers

An organic compound P having molecular formula C_6 H_6 O_3 gives...

An organic compound P\mathbf{P} having molecular formula C6H6O3\mathrm{C}_6 \mathrm{H}_6 \mathrm{O}_3 gives ferric chloride test and does not have intramolecular hydrogen bond. The compound P\mathbf{P} reacts with 3 equivalents of NH2OH\mathrm{NH}_2 \mathrm{OH} to produce oxime Q\mathbf{Q}. Treatment of P\mathbf{P} with excess methyl iodide in the presence of KOH\mathrm{KOH} produces compound R\mathbf{R} as the major product. Reaction of R\mathbf{R} with excess iso-butylmagnesium bromide followed by treatment with H3O+\mathrm{H}_3 \mathrm{O}^{+}gives compound S\mathrm{S} as the major product. The total number of methyl (−CH3)\left(-\mathrm{CH}_3\right) group(s) in compound S\mathbf{S} is ________. (consider maximum value if there are two values)An organic compound P having molecular formula C_6 H_6 O_3 gives ferric chloride test and does not have intramolecularAn organic compound P having molecular formula C_6 H_6 O_3 gives ferric chloride test and does not have intramolecular

Correct answer

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Step-by-step solution

An organic compound P having molecular formula C_6 H_6 O_3 gives ferric chloride test and does not have intramolecular No. of −CH3-\mathrm{CH}_3 group (methyl group) in S\mathrm{S} is →12\rightarrow 12 Alternative solution organic compound P=C6H6O3\mathrm{P}=\mathrm{C}_6 \mathrm{H}_6 \mathrm{O}_3 positive test with FeCl3\mathrm{FeCl}_3An organic compound P having molecular formula C_6 H_6 O_3 gives ferric chloride test and does not have intramolecular Total number of methyl group =6+2=8=6+2=8 and if only main organic product is taken than number of methyl group =6=6 (side product is not consider)
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