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JEE Advanced 2024Paper 1
Exam
JEE Advanced
Year
2024
Paper
Paper 1
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Advanced 2024 · Paper 1 · Chemistry · Alcohols Phenols and Ethers

Complete reaction of acetaldehyde with excess formaldehyde, upon...

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH\mathrm{NaOH} solution, gives PandQ\mathbf{P} and \mathbf{Q}. Compound P\mathbf{P} does not give Tollens' test, whereas Q\mathbf{Q} on acidification gives positive Tollens' test. Treatment of P\mathbf{P} with excess cyclohexanone in the presence of catalytic amount of pp-toluenesulfonic acid (PTSA) gives product R\mathbf{R}. Sum of the number of methylene groups (−CH2−)\left(-\mathrm{CH}_2-\right) and oxygen atoms in R\mathbf{R} is ________.Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH solution, gives P and Q .

Correct answer

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Step-by-step solution

Complete reaction of acetaldehyde with excess formaldehyde, upon heating with conc. NaOH solution, gives P and Q . Total CH2\mathrm{CH}_2 in R=14\mathrm{R}=14 and oxygen in R=4\mathrm{R}=4 So 14+4=1814+4=18
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