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JEE Advanced 2023Paper 2
Exam
JEE Advanced
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Advanced 2023 · Paper 2 · Chemistry · Alcohols Phenols and Ethers

A trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on...

A trinitro compound, 1,3,51, 3, 5-tris-(44-nitrophenyl) benzene, on complete reaction with an excess of Sn/HClSn / HCl gives a major product, which on treatment with an excess of NaNO2/HCl{NaNO}_{2} / HCl at 0°C0 ° C provides PP as the product. PP, upon treatment with excess of H2O{H}_{2}O at room temperature, gives the product QQ. Bromination of QQ in aqueous medium furnishes the product RR. The compound PP upon treatment with an excess of phenol under basic conditions gives the product SS. The molar mass difference between compounds QQ and RR is 474gmol−1474g{mol}^{- 1} and between compounds PP and SS is 172.5gmol−1172 . 5g{mol}^{- 1}.
The number of heteroatoms present in one molecule of RR is [Use: Molar mass (in g mol-1): H=1,C=12,N=14,O=16,Br=80,Cl=35.5H = 1, C = 12, N = 14, O = 16, Br = 80, Cl = 35 . 5 Atoms other than CC and HH are considered as heteroatoms]A trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on complete reaction with an excess of Sn / HCl gives aA trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on complete reaction with an excess of Sn / HCl gives aA trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on complete reaction with an excess of Sn / HCl gives a

Correct answer

0

Step-by-step solution

Nitrobenzene part converts to aniline part using Sn/HClSn / HCl. Aniline forms diazonium salt with nitrous acid and hydrogen chloride. Diazonium salt forms phenol with warm water.Phenol forms poly substituted bromo compound with bromine water.

A trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on complete reaction with an excess of Sn / HCl gives a

A trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on complete reaction with an excess of Sn / HCl gives a

A trinitro compound, 1, 3, 5 -tris-( 4 -nitrophenyl) benzene, on complete reaction with an excess of Sn / HCl gives a

The hetero atoms present the product RRare 6 bromine atoms and 3 oxygen atoms. Number of Hetero atoms in RR is 99.

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