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JEE Advanced 2010Paper 1
Exam
JEE Advanced
Year
2010
Paper
Paper 1
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Advanced 2010 · Paper 1 · Chemistry · Alcohols Phenols and Ethers

In the reaction, the intermediate(s) is (are)

In the reaction, the intermediate(s) is (are) In the reaction, the intermediate(s) is (are)

Options

  1. AParagraph According to Maxwell distribution law, the probability distribution function is given as below: F(v)=4 π( M 2
  2. BParagraph According to Maxwell distribution law, the probability distribution function is given as below: F(v)=4 π( M 2
  3. CParagraph According to Maxwell distribution law, the probability distribution function is given as below: F(v)=4 π( M 2
  4. DParagraph According to Maxwell distribution law, the probability distribution function is given as below: F(v)=4 π( M 2

Correct answer

A. Paragraph According to Maxwell distribution law, the probability distribution function is given as below: F(v)=4 π( M 2

Step-by-step solution

In the reaction, the intermediate(s) is (are)
- OH\mathrm{OH} and in aqueous in alkaline medium −O‾-\overline{\mathrm{O}} are ortho and para directing. We expect the main intermediate products as mono ortho/para substituted product. Remember! if we consider (b), which could be there in small amount then we need to consider even (d) because −O‾-\overline{\mathrm{O}} is strongest activating group that facilitates electrophilic substitution reaction overall on the ring. −O‾-\overline{\mathrm{O}} activates ortho and para position more but doesn't deactivate the meta position. We get a small amount of even the meta substituted product. But, as the question appears to be directly concerned answer should be only (a) and (c). Reaction mechanism (Electrophilic substitution) Conceptual II
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