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JEE Advanced 2022Paper 1
Exam
JEE Advanced
Year
2022
Paper
Paper 1
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Advanced 2022 · Paper 1 · Chemistry · Carboxylic Acid Derivatives

Considering the reaction sequence given below, the correct...

Considering the reaction sequence given below, the correct statement(s) is(are)

Considering the reaction sequence given below, the correct statement(s) is(are)

Options

  1. APP can be reduced to a primary alcohol using NaBH4{NaBH}_{4}.
  2. BTreating PP with conc. NH4OH{NH}_{4}OH solution followed by acidification gives QQ.
  3. CTreating QQ with a solution of NaNO2{NaNO}_{2} in aq.HClaq . HCl liberates N2{N}_{2}.
  4. DPP is more acidic than CH3CH2COOH{CH}_{3}{CH}_{2}COOH.

Correct answer

B. Treating PP with conc. NH4OH{NH}_{4}OH solution followed by acidification gives QQ.

Step-by-step solution

Propanoic acid is having α-hydrogen hence it is halogenated at the α-position on treatment with chlorine or bromine in the presence of small amount of red phosphorus to give α-bromo propanoic acid. The reaction is known as Hell-Volhard-Zelinsky reaction.

Second step of the reaction involves Gabriel phthalimide synthesis Where potassium salt of phthalimide which on heating with 2-bromo propanoic acid followed by alkaline hydrolysis produces the corresponding 2-amino propanoic acid. Aromatic primary amines cannot be prepared by this method.Considering the reaction sequence given below, the correct statement(s) is(are)

NaBH4{NaBH}_{4} cannot reduce the acids.

Conc . {NH}_{4}OHexistinthefollowingequilibrium,</p><p>exist in the following equilibrium,</p><p>{NH}_{4}^{+} + {OH}^{-} ⇋ {NH}_{3} + {H}_{2}O

Considering the reaction sequence given below, the correct statement(s) is(are)

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