- Exam
- JEE Advanced
- Year
- 2022
- Paper
- Paper 1
- Subject
- Chemistry
- Chapter
- Carboxylic Acid Derivatives
JEE Advanced 2022 · Paper 1 · Chemistry · Carboxylic Acid Derivatives
Considering the reaction sequence given below, the correct...
Considering the reaction sequence given below, the correct statement(s) is(are)
Options
- A can be reduced to a primary alcohol using .
- BTreating with conc. solution followed by acidification gives .
- CTreating with a solution of in liberates .
- D is more acidic than .
Correct answer
B. Treating with conc. solution followed by acidification gives .
Step-by-step solution
Propanoic acid is having α-hydrogen hence it is halogenated at the α-position on treatment with chlorine or bromine in the presence of small amount of red phosphorus to give α-bromo propanoic acid. The reaction is known as Hell-Volhard-Zelinsky reaction.
Second step of the reaction involves Gabriel phthalimide synthesis Where potassium salt of phthalimide which on heating with 2-bromo propanoic acid followed by alkaline hydrolysis produces the corresponding 2-amino propanoic acid. Aromatic primary amines cannot be prepared by this method.
cannot reduce the acids.
Conc . {NH}_{4}OH{NH}_{4}^{+} + {OH}^{-} ⇋ {NH}_{3} + {H}_{2}O