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JEE Main 202330 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
30 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Main 2023 · 30 January · Morning Shift · Chemistry · Carboxylic Acid Derivatives

A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral...

A trisubstituted compound 'AA', C10H12O2{C}_{10}{H}_{12}{O}_{2} gives neutral FeCl3{FeCl}_{3} test positive. Treatment of compound 'AA' with NaOHNaOH and CH3Br{CH}_{3}Br gives C11H14O2{C}_{11}{H}_{14}{O}_{2}, with hydroiodic acid gives methyl iodide and with hot conc. NaOHNaOH gives a compound BB, C10H12O2{C}_{10}{H}_{12}{O}_{2}. Compound 'AA' also decolorises alkaline KMnO4{KMnO}_{4}. The number of π\pi bond/s present in the compound 'AA' is _____ .A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A 'A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A 'A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A 'A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A '

Correct answer

0

Step-by-step solution

The trisubstituted compound 'AA', C10H12O2{C}_{10}{H}_{12}{O}_{2} gives neutral FeCl3{FeCl}_{3} test positive, means the compound is phenol. Phenol on treatment with NaOHNaOH and CH3Br{CH}_{3}Br gives C10H11O2CH3{C}_{10}{H}_{11}{O}_{2}{CH}_{3}. The given compound is reacting with hot conc. NaOHNaOH gives a compound BB, C10H12O2{C}_{10}{H}_{12}{O}_{2}. The reaction is Cannizzaro's reaction. Hence, compound must be benzaldehyde derivative. Compound 'AA' also decolourises alkaline KMnO4{KMnO}_{4}, means compound contains an alkyl group attached to benzene ring. Hence, the structure of the compound can be written as follows,

A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A '

The reactions are shown below.

A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A '

A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A '

A trisubstituted compound ' A ', C _ 10 H _ 12 O _ 2 gives neutral FeCl _ 3 test positive. Treatment of compound ' A '

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