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JEE Advanced 2009Paper 1
Exam
JEE Advanced
Year
2009
Paper
Paper 1
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Advanced 2009 · Paper 1 · Chemistry · Chemical Bonding and Molecular Structure

Match each of the diatomic molecules in Column I with its...

Match each of the diatomic molecules in Column I with its property/properties in Column II. Match each of the diatomic molecules in Column I with its property/properties in Column II.

Options

  1. A(A) q,t, (B) s,t, (C) r,t, (D) p,q,s
  2. B(A) p,q,s,t, (B) p,s,t, (C) p,q, (D) r,s
  3. C(A) p,r,t, (B) s,t, (C) p,q,r, (D) p,r,s
  4. D(A) p,q,s,t, (B) p,s,t, (C) p,q, (D) r,s

Correct answer

C. (A) p,r,t, (B) s,t, (C) p,q,r, (D) p,r,s

Step-by-step solution

- A. B2B_2 : Has two unpaired electrons, making it p. Paramagnetic. The close energy levels of 2s2 s and 2p2 p orbitals lead to (t.s−p\mathrm{t.s - p}) mixing. - B. (\boldsymbol{N}_{\mathrm{2}}) : Has a bond order of (3\mathrm{3}), so its bond order is (s\mathrm{s}). (≥2\mathrm{\geq 2}). It also has (t.s−p\mathrm{t . s - p}) mixing and can gain electrons, so it r. Undergoes reduction. - C. O2O_2 : Has two unpaired electrons, making it p. Paramagnetic. Its bond order is 2 , so it's (s\mathrm{s}). (\geq) 2. With electrons in antibonding orbitals, it can lose electrons, thus q. Undergoing oxidation. - D. O2−O_2^{-}: Has one unpaired electron, making it p. Paramagnetic. It can both gain and lose electrons, so it q. Undergoes oxidation and r. Undergoes reduction. The correct option is (3).
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