JEE Advanced 2026Paper 1
- Exam
- JEE Advanced
- Year
- 2026
- Paper
- Paper 1
- Subject
- Chemistry
- Chapter
- Coordination Compounds
JEE Advanced 2026 · Paper 1 · Chemistry · Coordination Compounds
The total number of all possible isomers for the square planar...
The total number of all possible isomers for the square planar complex with formula is ____.
( = metal ion and gly = )
( = metal ion and gly = )
Correct answer
0
Step-by-step solution
The given complex is . The complex anion is .
The ligands present in the complex are:
1. (glycinate): An unsymmetrical bidentate ligand coordinating through nitrogen (N) and oxygen (O). Let this be represented as .
2. : An ambidentate monodentate ligand that can coordinate through nitrogen () or sulfur ().
3. : An ambidentate monodentate ligand that can coordinate through nitrogen () or oxygen ().
First, we find the number of linkage isomers due to the ambidentate ligands:
has 2 linkage modes (N or S).
has 2 linkage modes (N or O).
Number of linkage combinations = .
For each linkage combination, the complex is of the type , where and are monodentate ligands and is an unsymmetrical bidentate ligand.
In a square planar geometry, the bidentate ligand must occupy adjacent (cis) positions. The monodentate ligands and will occupy the remaining two positions.
This gives rise to 2 geometrical isomers for each linkage combination:
1. Ligand is trans to A (and is trans to B).
2. Ligand is trans to B (and is trans to A).
Since square planar complexes of this type possess a molecular plane of symmetry, they do not exhibit optical isomerism.
Total number of isomers = (Number of linkage combinations) (Number of geometrical isomers per combination)
Total isomers = .
Answer:
The ligands present in the complex are:
1. (glycinate): An unsymmetrical bidentate ligand coordinating through nitrogen (N) and oxygen (O). Let this be represented as .
2. : An ambidentate monodentate ligand that can coordinate through nitrogen () or sulfur ().
3. : An ambidentate monodentate ligand that can coordinate through nitrogen () or oxygen ().
First, we find the number of linkage isomers due to the ambidentate ligands:
has 2 linkage modes (N or S).
has 2 linkage modes (N or O).
Number of linkage combinations = .
For each linkage combination, the complex is of the type , where and are monodentate ligands and is an unsymmetrical bidentate ligand.
In a square planar geometry, the bidentate ligand must occupy adjacent (cis) positions. The monodentate ligands and will occupy the remaining two positions.
This gives rise to 2 geometrical isomers for each linkage combination:
1. Ligand is trans to A (and is trans to B).
2. Ligand is trans to B (and is trans to A).
Since square planar complexes of this type possess a molecular plane of symmetry, they do not exhibit optical isomerism.
Total number of isomers = (Number of linkage combinations) (Number of geometrical isomers per combination)
Total isomers = .
Answer: