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JEE Advanced 2026Paper 1
Exam
JEE Advanced
Year
2026
Paper
Paper 1
Subject
Chemistry
Chapter
Coordination Compounds

JEE Advanced 2026 · Paper 1 · Chemistry · Coordination Compounds

The total number of all possible isomers for the square planar...

The total number of all possible isomers for the square planar complex with formula K[M(NCS)(NO2)(gly)]\text{K}[\text{M(NCS)(NO}_2\text{)(gly)}] is ____.
(MM = metal ion and gly = NH2CH2COO−\text{NH}_2\text{CH}_2\text{COO}^-)

Correct answer

0

Step-by-step solution

The given complex is K[M(NCS)(NO2)(gly)]\text{K}[\text{M(NCS)(NO}_2\text{)(gly)}]. The complex anion is [M(NCS)(NO2)(gly)]−[\text{M(NCS)(NO}_2\text{)(gly)}]^{-}.

The ligands present in the complex are:
1. gly−\text{gly}^- (glycinate): An unsymmetrical bidentate ligand coordinating through nitrogen (N) and oxygen (O). Let this be represented as (AB)(AB).
2. NCS−\text{NCS}^-: An ambidentate monodentate ligand that can coordinate through nitrogen (-NCS\text{-NCS}) or sulfur (-SCN\text{-SCN}).
3. NO2−\text{NO}_2^-: An ambidentate monodentate ligand that can coordinate through nitrogen (-NO2\text{-NO}_2) or oxygen (-ONO\text{-ONO}).

First, we find the number of linkage isomers due to the ambidentate ligands:
NCS−\text{NCS}^- has 2 linkage modes (N or S).
NO2−\text{NO}_2^- has 2 linkage modes (N or O).
Number of linkage combinations = 2×2=42 \times 2 = 4.

For each linkage combination, the complex is of the type [M(a)(b)(AB)][\text{M}(a)(b)(AB)], where aa and bb are monodentate ligands and ABAB is an unsymmetrical bidentate ligand.
In a square planar geometry, the bidentate ligand (AB)(AB) must occupy adjacent (cis) positions. The monodentate ligands aa and bb will occupy the remaining two positions.
This gives rise to 2 geometrical isomers for each linkage combination:
1. Ligand aa is trans to A (and bb is trans to B).
2. Ligand aa is trans to B (and bb is trans to A).

Since square planar complexes of this type possess a molecular plane of symmetry, they do not exhibit optical isomerism.

Total number of isomers = (Number of linkage combinations) ×\times (Number of geometrical isomers per combination)
Total isomers = 4×2=84 \times 2 = 8.

Answer: 88
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