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JEE Coordination Compounds PYQs with Solutions

715 previous year questions from Coordination Compounds (JEE Main & Advanced Chemistry) with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

715 questionsChemistry2006–2026Answers + solutions

About Coordination Compounds PYQs

Coordination Compounds has 715 previous year questions in the Quantrex Academy JEE Main & Advanced Chemistry bank. The 220 questions in this list come from JEE Main (167) and JEE Advanced (53), spanning 2006 to 2026. Each question opens on its own page with the options, the correct answer and the worked solution where available.

Questions by year (this list)

  • 2026: 36
  • 2025: 41
  • 2024: 45
  • 2023: 55
  • 2022: 2
  • 2021: 3
  • 2020: 1
  • 2019: 1
  • 2018: 3
  • 2017: 1
  • 2016: 3
  • 2015: 3

Coordination Compounds questions with solutions

1

Reaction of PtF_6 with oxygen ( O_2 ) gas results in the formation of an ionic compound, X^+Y^- . Correct statement(s) is(are)

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2

The total number of all possible isomers for the square planar complex with formula K[M(NCS)(NO_2)(gly)] is ____. ( M = metal ion and gly = NH_2CH_2COO^- )

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3

Consider that the coordinating atoms of the ligands in cis -[Co(NH _3 ) _4 Cl _2 ]Cl and mer -[Co(NH _3 ) _3 Cl _3 ] octahedral complexes are at the vertices of an octahedron. The

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4

Number of paramagnetic complexes among the following is ________. [MnBr_4]^ 2- , [NiCl_4]^ 2- , [Ni(CN)_4]^ 2- , [Ni(CO)_4] , [CoF_6]^ 3- , [Fe(CN)_6]^ 4- , [Mn(CN)_6]^ 3

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5

Which of the following sequences of hybridisation, geometry and magnetic nature are correct for the given coordination compounds ? A. [NiCl_4]^ 2- - sp ^3 , tetrahedral

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6

An excess of AgNO _3 is added to 100 mL of a 0.05 M solution of tetraaquadichloridochromium (III) chloride. The number of moles of AgCl precipitated will be __________ × 10^ -3 .

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7

Match the LIST-I with LIST-II List-I Electronic configuration of tetrahedral metal ion List-II Crystal Field Stabilization Energy ( Δ_t ) A. d^2 I. -0.6 B. d^4 II. -0.8 C. d^6

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8

Which of the following are true about the energy of the given d-orbitals of a tetrahedral complex? A. d_ xy = d_ xz > d_ x^2-y^2 B. d_ xy = d_ yz > d_ z^2 C. d_ x^2-y^2 > d_ z^2 >

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9

Identify the correct statements from the following A. [Fe(C_2O_4)_3]^ 3- is the most stable complex among [Fe(OH)_6]^ 3- , [Fe(C_2O_4)_3]^ 3- and [Fe(SCN)_6]^ 3- B. The stability

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10

The total number of unpaired electrons present in the d^3 , d^4 (low spin), d^5 (high spin), d^6 (high spin) and d^7 (low spin) octahedral complex systems is _______.

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11

The correct statements about metal carbonyls are A. The metal-carbon bonds in metal carbonyls possess both σ and π -character. B. Due to synergic bonding interactions between

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12

Given below are two statements: Statement I: Each electron in e_g orbitals destabilizes the orbitals by +0.6Δ_o and each electron in the t_ 2g orbitals stabilizes the orbitals by

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13

Consider the metal complexes [Ni(en)_3]^ 2+ (A), [NiCl_4]^ 2- (B) and [Ni(NH_3)_6]^ 2+ (C). Choose the CORRECT option by considering the number of unpaired electrons present in

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14

Match the LIST-I with LIST-II List-I Complex ion List-II Calculated spin only magnetic moment (BM) A. [Cr(H_2O)_6]^ 2+ I. 3.87 B. [Co(H_2O)_6]^ 2+ II. 5.92 C. [Cu(H_2O)_6]^ 2+

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15

Which of the following complexes will show coordination isomerism? A. [Ag(NH_3)_2][Ag(CN)_2] B. [Co(NH_3)_6][Cr(CN)_6] C. [Co(NH_3)_6][Co(CN)_6] D. [Fe(NH_3)_6][Co(CN)_6] E.

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16

Match List - I with List - II. List - I Chromium (III) Complexes (en = ethylene diamine) List - II Δ_0 (cm ^ -1 ) A. [Cr(CN)_6]^ 3- I. 15,060 B. [CrF_6]^ 3- II. 17,400 C.

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17

5.33 g of CrCl_3 · 6H_2O , which is a 1 : 3 electrolyte, is dissolved in water and is passed through a cation exchanger. The chloride ions in the eluted solution, on treatment

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18

The correct increasing order of spin-only magnetic moment values of the complex ions [MnBr_ 4 ]^ 2- (A),[Cu(H_ 2 O)_ 6 ]^ 2+ (B),[Ni(CN)_ 4 ]^ 2- (C) and [Ni(H_ 2 O)_ 6 ]^ 2+ (D)

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19

The number of isoelectronic species among Sc^ 3+ , Cr^ 2+ , Mn^ 3+ , Co^ 3+ and Fe^ 3+ is ' n^ . If ' n^ moles of AgCl is formed during the reaction of complex with formula CoCl_

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20

The correct statement among the following is:

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21

X is the number of geometrical isomers exhibited by [Pt(NH_ 3 )(H_ 2 O) BrCl] . Y is the number of optically inactive isomer(s) exhibited by [CrCl_ 2 (ox)_ 2 ]^ 3- Z is the number

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22

The wavelength of light absorbed for the following complexes are in the order \( (I) [Co(NH _ 3 )_6]^ 3+ ; (II) [Co(H _ 2 O)_ 6]^ 3+ ; (III) [Co(CN)_ 6]^ 3- ; (IV) [Co(NH _ 3

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23

A chromium complex with a formula CrCl_ 3 · 6 H_ 2 O has a spin only magnetic moment value of 3.87 BM and its solution conductivity corresponds to 1: 2 electrolyte. 2.75 g of the

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24

Given below are two statements: Statement I : Hybridisation, shape and spin only magnetic moment of K_ 3 [Co(CO_ 3 )_ 3 ] is sp^ 3 ~d^ 2 , octahedral and 4.9 BM respectively.

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25

Given below are two statements: Statement I : The number of paramagnetic species among [CoF_ 6 ]^ 3- ,[TiF_ 6 ]^ 3- , V_ 2 O_ 5 and [Fe(CN)_ 6 ]^ 3- is 3. Statement II : K_ 4

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26

Consider a mixture ' X ' which is made by dissolving 0.4 mol of [Co(NH_ 3 )_ 5 SO_ 4 ] Br and 0.4 mol of [Co(NH_ 3 )_ 5 Br] SO_ 4 in water to make 4 L of solution. When 2 L of

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27

Identify the CORRECT set of details from the following: A. [Co(NH_ 3 )_ 6 ]^ 3+ : Inner orbital complex; d^ 2 sp^ 3 hybridized B. [MnCl_ 6 ]^ 3- : Outer orbital complex; sp^ 3 ~d^

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28

Total number of unpaired electrons present in the central metal atoms/ions of [Ni(CO)_ 4 ],[NiCl_ 4 ]^ 2- ,[PtCl_ 2 (NH_ 3 )_ 2 ],[Ni(CN)_ 4 ]^ 2- and [Pt(CN)_ 4 ]^ 2- is \_\_\_\_

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29

Given below are two statements : Statement I : [CoBr_ 4 ]^ 2- ion will absorb light of lower energy than [CoCl_ 4 ]^ 2- ion. Statement II : In [CoI_ 4 ]^ 2- ion, the energy

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30

The statements that are incorrect about the nickel(II) complex of dimethylglyoxime are : A. It is red in colour. B. It has a high solubility in water at pH=9 . C. The Ni ion has

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31

The crystal field splitting energy of [Co( oxalate )_ 3 ]^ 3- complex is ' n^ times that of the [Cr( oxalate )_ 3 ]^ 3- complex. Here ' n^ is \_\_\_\_ . (Assume Δ_ 0 P )

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32

[Ni(PPh_ 3 )_ 2 Cl_ 2 ] is a paramagnetic complex. Identify the INCORRECT statements about this complex. A. The complex exhibits geometrical isomerism. B. The complex is white in

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33

Consider the transition metal ions Mn^ 3+ , Cr^ 3+ , Fe^ 3+ and Co^ 3+ and all form low spin octahedral complexes. The correct decreasing order of unpaired electrons in their

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34

Given below are two statements : Statement I : Crystal Field Stabilization Energy (CFSE) of [Cr(H_ 2 O)_ 6 ]^ 2+ is greater than that of [Mn(H_ 2 O)_ 6 ]^ 2+ . Statement II

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35

Identify the metal ions among Co^ 2+ , Ni^ 2+ , Fe^ 2+ , V^ 3+ and Ti^ 2+ having a spin-only magnetic moment value more than 3.0 BM. The sum of unpaired electrons present in the

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36

Given below are two statements : Statement I : Among .[Cu(NH_ 3 )_ 4 ]^ 2+ ,[Ni(en)_ 3 )]^ 2+ ,[Ni(NH_ 3 )_ 6 ]^ 2+ and [Mn(H_ 2 O)_ 6 ]^ 2+ , [Mn(H_ 2 O)_ 6 ]^ 2+ has the maximum

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37

The correct order of the wavelength maxima of the absorption band in the ultraviolet-visible region for the given complexes is

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38

The sum of the spin only magnetic moment values (in B.M.) of [Mn(Br)_6]^ 3- and [Mn(CN)_6]^ 3- is _____.

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39

Given below are two statements : Statement I : A homolepitc octahedral complex, formed using monodentate ligands, will not show stereoisomerism. Statement II : cis- and trans

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40

Match the List-I with List-II List-I (Complex/ Species) List-II (Shape magnetic moment) A. [ Ni(CO)_4] I. Tetrahedral, 2.8 BM B. [ Ni(CN)_4]^ 2- II. Square planar, 0 BM C. [

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41

Match List-I with List-II Choose the correct answer from the options given below :

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42

The number of unpaired electrons responsible for the paramagnetic nature of the following complex species are respectively: [Fe(CN)_6]^ 3- ,[FeF_6]^ 3- ,[CoF_6]^ 3- ,[Mn(CN)_6]^ 3-

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43

The number of paramagnetic metal complex species among [Co(NH_3)_6]^ 3+ , [Co(C_2 O_4)_3]^ 3- , [MnCl_6]^ 3- ,[Mn(CN)_6]^ 3- ,[CoF_6]^ 3- ,[Fe(CN)_6]^ 3^ 3- and [FeF_6]^ 3- with

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44

An octahedral complex having molecular composition Co. 5 NH_3. Cl. SO_4 has two isomers A and B. The solution of A gives a white precipitate with AgNO_3 solution and the solution

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45

The number of paramagnetic complex among [FeF_6]^ 3- ,[Fe(CN)_6]^ 3- ,[Mn(CN)_6]^ 3- ,[Co(C_2 O_4)_3]^ 3- , [MnCl_6]^ 3- and [CoF_6]^ 3- , which involved d^2 sp^3 hybridization is

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46

The correct order of [FeF_6]^ 3- ,[CoF_6]^ 3- ,[Ni(CO)_4] and [Ni(CN)_4]^ 2- complex species based on the number of unpaired electrons present is :

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47

' X ' is the number of electrons in t_ 2 g orbitals of the most stable complex ion among [Fe(NH_3)_6]^ 3+ , [Fe(Cl_6)]^ 3- ,[Fe(C_2 O_4)_3]^ 3- and [Fe(H_2 O)_6]^ 3+ . The nature

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48

Number of stereoisomers possible for the complexes, [CrCl_3(py)_3] and [CrCl_2(ox)_2]^ 3- are respectively ( py= pyridine, ox= oxalate)

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49

Which one of the following complexes will have Δ_0=0 and μ=5.96 B.M.?

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50

Identify the diamagnetic octahedral complex ions from below ; A. [Mn(CN)_6]^ 3- B. [Co(NH_3)_6]^ 3+ C. [Fe(CN)_6]^ 4- D. [Co(H_2 O)_3 ~F_3] Choose the correct answer from the

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51

The number of optical isomers exhibited by the iron complex (A) obtained from the following reaction is ________ FeCl_3+KOH+H_2 C_2 O_4 arrow ~A

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52

Match the LIST-I with LIST-II Choose the correct answer from the options given below :

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53

The correct order of the complexes [Co(NH_3)_5(H_2 O)]^ 3+ (A), [Co(NH_3)_6]^ 3+ (B), [Co(CN)_6]^ 3- (C) and [CoCl(NH_3)_5]^ 2+ (D) in terms wavelength of light absorbed is :

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54

The d-orbital electronic configuration of the complex among [Co(en)_3]^ 3+ , [CoF_6]^ 3- , [Mn(H_2 O)_6]^ 2+ and [Zn(H_2 O)_6]^ 2+ that has the highest CFSE is :

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55

The type of hybridization and the magnetic property of [MnCl_6]^ 3- are :

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56

The spin-only magnetic moment value of M^ n+- ion formed among Ni, Zn Mn and Cu that has the least enthalpy of atomisation is ________. (in nearest integer) Here n is equal to the

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57

Given below are two statements : Statement (I) : In octahedral complexes, when \(Δ_ o P\) high spin complexes are formed. When \(Δ_ o P\) low spin complexes are formed. Statement

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58

A transition metal \(( M) among \( Mn, Cr, Co and Fe has the highest standard electrode potential \( (M^ 3+ / M^ 2+ )\). It forms a metal complex of the type \([M(CN)_ 6]^ 4- \).

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59

Identify the homoleptic complexes with odd number of d electrons in the central metal : (A) [FeO_4]^ 2- (B) [Fe(CN)_6]^ 3- (C) [Fe(CN)_5 NO]^ 2- (D) [CoCl_4]^ 2- (E) [Co(H_2 O)_3

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60

Consider the following low-spin complexes K_3[Co(NO_2)_6], K_4[Fe(CN)_6] , K_3[Fe(CN)_6], Cu u_2[Fe(CN)_6] and Zn_2[Fe(CN)_6] The sum of the spin-only magnetic moment values of

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61

Match List - I with List - II. \( array ll & - I & & - II & (Complex) & & (Hybridisation & Magnetic characters) (A) & [MnBr_4]^ 2- & (I) & d^2 s^3 & diamagnetic (B) & [FeF_6]^ 3

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62

The correct increasing order of stability of the complexes based on \(Δ_ o \) value is : I. \( [Mn(CN)_ 6]^ 3- \) II. \( [Co(CN)_ 6]^ 4- \) III. \( [Fe(CN)_ 6]^ 4- \) IV. \(

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63

Match List - I with List - II. Choose the correct answer from the options given below :

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64

The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead

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65

Match List - I with List - II. Choose the correct answer from the options given below :

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66

When Ethane-1,2-diamine is added progressively to an aqueous solution of Nickel (II) chloride, the sequence of colour change observed will be :

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67

The conditions and consequence that favours the t_ 2 g ^3 e_g^1 configuration in a metal complex are

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68

One mole of the octahedral complex compound Co(NH_3)_5 Cl_3 gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with excess of AgNO_3 solution to

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69

Identify the coordination complexes in which the central metal ion has d^4 configuration. Choose the correct answer from the options given below :

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70

The complex that shows Facial - Meridional isomerism is:

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71

CrCl_3 · xNH_3 can exist as a complex. 0.1 molal aqueous solution of this complex shows a depression in freezing point of 0.558^ ∘ C . Assuming 100 \% ionisation of this complex

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72

The d- electronic configuration of an octahedral Co(II) complex having magnetic moment of 3.95 BM is:

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73

The correct order of the following complexes in terms of their crystal field stabilization energies is :

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74

Identify the homoleptic complex(es) that is/are low spin. (A) [Fe(CN)_5 NO]^ 2- (B) [CoF_6]^ 3- (C) [Fe(CN)_6]^ 4- (D) [Co(NH_3)_6]^ 3+ (E) [Cr(H_2 O)_6]^ 2+ Choose the correct

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75

The complex of Ni^ 2+ ion and dimethyl glyoxime contains ________ number of Hydrogen (H) atoms.

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76

In which of the following complexes the CFSE, Δ_ o will be equal to zero?

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77

From the magnetic behaviour of [NiCl_4]^ 2- (paramagnetic) and [Ni(CO)_4] (diamagnetic), choose the correct geometry and oxidation state.

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78

Among [Co(CN)_4]^ 4- ,[Co(CO)_3(NO)], XeF_4,[PCl_4]^ + ,[PdCl_4]^ 2- ,[ICl_4]^ - ,[Cu(CN)_4]^ 3- and P_4 the total number of species with tetrahedral geometry is _______

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79

Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other. [en

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80

Among V(CO)_6, Cr(CO)_5, Cu(CO)_3, Mn(CO)_5, Fe(CO)_5,[Co(CO)_3]^ 3- ,[Cr(CO)_4]^ 4- , and Ir(CO)_3 , the total number of species isoelectronic with Ni(CO)_4 is ________. [Given

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81

Among the following complexes, the total number of diamagnetic species is_____ [Mn(NH_3)_6]^ 3+ ,[MnCl_6]^ 3- ,[FeF_6]^ 3- ,[CoF_6]^ 3- ,[Fe(NH_3)_6]^ 3+ , and [Co(en)_3]^ 3+

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82

Match List I with List II \( List - I List - II A. K_2 [ Ni(CN)_4] I. sp^3 B. [ Ni(CO)_4] II. sp^3 d² C. [ Co(NH_3)_6] Cl_3 III. dsp^2 D. Na_3 [ CoF_6] IV. d^2 sp^3 \) Choose the

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83

The coordination environment of \(Ca^ 2+ \) ion in its complex with \(EDTA^ 4- \) is :

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84

The \(F^ - \)ions make the enamel on teeth much harder by converting hydroxyapatite (the enamel on the surface of teeth) into much harder fluoroapatite having the formula.

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85

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A) : The total number of geometrical isomers shown by

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86

Number of ambidentate ligands among the following is ______ \( NO _ 2 ^ - , SCN^ - , C _ 2 O _ 4 ^ 2- , NH _ 3 , CN^ - , SO _ 4 ^ 2- , H _ 2 O \).

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87

Match List - I with List - II. \( List - I (Complex ion) List - II (Spin only magnetic moment in B.M.) (A) [ Cr(NH_3)_6]^ 3+ (I) 4.90 (B) [ NiCl_4]^ 2- (II) 3.87 (C) [ CoF_6]^ 3

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88

Total number of unpaired electrons in the complex ions \([Co(NH_3)_6]^ 3+ \) and \([NiCl_4]^ 2- \) is \( \)

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89

Number of Complexes with even number of electrons in \(t_ 2 g \) orbitals is - \( [Fe(H _ 2 O) _6]^ 2+ ,[Co(H _ 2 O)_ 6]^ 2+ , [Co(H _ 2 O) _6]^ 3+ ,[Cu(H _ 2 O)_ 6]^ 2+ ,[Cr(H _

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90

An octahedral complex with the formula \(CoCl_3 · nNH_3\) upon reaction with excess of \(AgNO_3\) solution gives 2 moles of \(AgCl\). Consider the oxidation state of \(Co\) in the

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91

The correct IUPAC name of \([PtBr_2(PMe_3)_2]\) is :

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92

Given below are two statements : Statement I : \( PF _ 5 \) and \( BrF _ 5 \) both exhibit \( sp^ 3 ~d \) hybridisation. Statement II : Both \( SF _ 6 \) and \([Co(NH _ 3 )_6]^ 3+

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93

Match List - I with List - II. \( List - I List - II Reaction Type of redox reaction (A) TiCl_4 (I) e², t_2^0 (B) [ FeO_4]^ 2- (II) e⁴, t_2^3 (C) [ FeCl_4]^ - (III) e⁰, t_2^0 (D)

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94

Match List I with List II \( List - I List - II (Compound) (Uses) A. Iodoform I. Fire extinguisher B. Carbon tetrachloride II. Insecticide C. CFC III. Antiseptic D. DDT IV.

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95

he following complexes \( (A) [CoCl(NH_ 3 )_5]^ 2+ , (B) [Co(CN)_6]^ 3- , (C) [Co(NH_ 3 )_5 (H_ 2 O)]^ 3+ , (D) [Cu(H_ 2 O)_ 4]^ 2+ \) The correct order of A, B, C and D in terms

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96

The number of complexes from the following with no electrons in the \(t_2\) orbital is \( \) \(TiCl_4,[MnO_4]^ - ,[FeO_4]^ 2- ,[FeCl_4]^ - ,[CoCl_4]^ 2- \)

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97

The metal atom present in the complex MABXL (where A, B, X and L are unidentate ligands and \(M\) is metal) involves \(sp^3\) hybridization. The number of geometrical isomers

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98

Which one of the following complexes will exhibit the least paramagnetic behaviour? [Atomic number, \( Cr= 24, Mn= 25, Fe= 26, Co= 27\) ]

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99

The correct order of ligands arranged in increasing field strength.

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100

If an iron (III) complex with the formula \([Fe(NH_3)_x(CN)_y]^ - \)has no electron in its \(e_g\) orbital, then the value of \(x+y\) is

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101

The number of unpaired d-electrons in \([Co(H_2 O)_6]^ 3+ \) is

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102

Number of complexes from the following with even number of unpaired " \(d\) " electrons is \( \) \([V(H_2 O)_6]^ 3+ ,[Cr(H_2 O)_6]^ 2+ ,[Fe(H_2 O)_6]^ 3+ ,[Ni(H_2 O)_6]^ 3+

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103

The correct sequence of ligands in the order of decreasing field strength is :

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104

Given below are two statements : Statement (I) : Dimethyl glyoxime forms a six membered covalent chelate when treated with NiCl _ 2 solution in presence of NH _ 4 OH . Statement

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105

[Co ( NH _ 3 ) _ 6 ] ^ 3 + and [ CoF _ 6 ] ^ 3 - are respectively known as:

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106

Which of the following complex is homoleptic?

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107

Given below are two statements: Statement (I): A solution of [Ni ( H _ 2 O) _ 6 ] ^ 2 + is green in colour. Statement (II): A solution of [Ni ( CN ) _ 4 ] ^ 2 - is colourless. In

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108

Select the option with correct property:

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109

Match List I with List II LIST – I (Complex ion) LIST – II (Electronic Configuration A. [Cr ( H _ 2 O) _ 6 ] ^ 3 + I. t _ 2g ^ 2 e _ g ^ 0 B. [Fe ( H _ 2 O) _ 6 ] ^ 3 + II. t _ 2g

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110

The correct statements from the following are: A. The strength of anionic ligands can be explained by crystal field theory. B. Valence bond theory does not give a quantitative

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111

The molecule/ion with square pyramidal shape is:

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112

Number of complexes which show optical isomerism among the following is _________. cis - [Cr ( ox ) _ 2 Cl _ 2 ] ^ 3 - , [Co ( en ) _ 3 ] ^ 3 + , cis - [Pt ( en ) _ 2 Cl _ 2 ] ^ 2

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113

The coordination geometry around the manganese in decacarbonyldimanganese (0)

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114

Choose the correct Statements from the following: (A) Ethane - 1, 2 - diamine is a chelating ligand. (B) Metallic aluminium is produced by electrolysis of aluminium oxide in

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115

Aluminium chloride in acidified aqueous solution forms an ion having geometry

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116

The correct IUPAC name of K _ 2 MnO _ 4 is:

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117

In which one of the following metal carbonyls, CO forms a bridge between metal atoms?

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118

Identity the incorrect pair from the following:

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119

Identify from the following species in which d ^ 2 sp ^ 3 hybridization is shown by central atom:

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120

The Spin only magnetic moment value of square planar complex [Pt ( NH _ 3 ) _ 2 Cl( NH _ 2 CH _ 3 )]Cl is _______ B.M. (Nearest integer) ( Given atomic number for Pt = 78 )

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