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JEE Main 20266 AprilMorning Shift
Exam
JEE Main
Year
2026
Date
6 April
Shift
Morning Shift
Subject
Chemistry
Chapter
Coordination Compounds

JEE Main 2026 · 6 April · Morning Shift · Chemistry · Coordination Compounds

Which of the following are true about the energy of the given...

Which of the following are true about the energy of the given d-orbitals of a tetrahedral complex?
A. dxy=dxz>dx2−y2d_{xy} = d_{xz} > d_{x^2-y^2}
B. dxy=dyz>dz2d_{xy} = d_{yz} > d_{z^2}
C. dx2−y2>dz2>dxzd_{x^2-y^2} > d_{z^2} > d_{xz}
D. dx2−y2=dz2<dxzd_{x^2-y^2} = d_{z^2} < d_{xz}

Choose the correct answer from the given below:

Options

  1. AA, B and D only
  2. BA and B only
  3. CB and D only
  4. DB, C and D only

Correct answer

A. A, B and D only

Step-by-step solution

In a tetrahedral complex, the five d-orbitals split into two sets due to the crystal field created by the ligands.

The ligands approach the central metal ion between the axes. The dxyd_{xy}, dyzd_{yz}, and dxzd_{xz} orbitals (forming the t2t_2 set) point between the axes, experiencing greater repulsion from the ligands, and thus have higher energy.

The dx2−y2d_{x^2-y^2} and dz2d_{z^2} orbitals (forming the ee set) point along the axes, experiencing lesser repulsion, and thus have lower energy.

Therefore, the energy order is dxy=dyz=dxz>dx2−y2=dz2d_{xy} = d_{yz} = d_{xz} > d_{x^2-y^2} = d_{z^2}.

Evaluating the given statements:
A. dxy=dxz>dx2−y2d_{xy} = d_{xz} > d_{x^2-y^2} is true.
B. dxy=dyz>dz2d_{xy} = d_{yz} > d_{z^2} is true.
C. dx2−y2>dz2>dxzd_{x^2-y^2} > d_{z^2} > d_{xz} is false.
D. dx2−y2=dz2<dxzd_{x^2-y^2} = d_{z^2} < d_{xz} is true.

Hence, statements A, B, and D are true.

Answer: A, B and D only
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