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JEE Advanced 2023Paper 1
Exam
JEE Advanced
Year
2023
Paper
Paper 1
Subject
Chemistry
Chapter
d and f Block Elements

JEE Advanced 2023 · Paper 1 · Chemistry · d and f Block Elements

In the scheme given below, X and Y , respectively, are Metal halide...

In the scheme given below, XX and YY, respectively, are

Metal halide→aq.NaOHWhite precipitate(P)+Filtrate(Q)\text{Metal halide}\overset{aq . NaOH}{\to}\text{White precipitate}\left(P\right) + \text{Filtrate}\left(Q\right)

P⟶PbO2(excess)aq.H2SO4heatX(a coloured species in solution)P\mathop{\overset{aq . {H}_{2}{SO}_{4}}{\overset{{PbO}_{2} ( excess )}{⟶}}}_{heat}X\left(\text{a coloured species in solution}\right)

Q⟶MnO(OH)2,Conc.H2SO4warmY(gives blue-coloration withKI−starch paper)Q\mathop{\overset{MnO ( OH{)}_{2}, Conc . {H}_{2}{SO}_{4}}{⟶}}_{warm}Y\left(\text{gives blue-coloration with}KI - \text{starch paper}\right)

Options

  1. ACrO42−{CrO}_{4}^{2 -} and Br2{Br}_{2}
  2. BMnO42−andCl2{MnO}_{4}^{2 -}and{Cl}_{2}
  3. CMnO4−andCl2{MnO}_{4}^{-}and{Cl}_{2}
  4. DMnSO4andHOCl{MnSO}_{4}andHOCl

Correct answer

C. MnO4−andCl2{MnO}_{4}^{-}and{Cl}_{2}

Step-by-step solution

The metal halide can be manganese dichloride. It gives white precipitate of manganese hydroxide.

MnCl2→aq.NaOHMn(OH)2(P)+NaCl(Q){MnCl}_{2}\overset{aq . NaOH}{\to}\mathop{Mn{\left(OH\right)}_{2}}_{\left(P\right)} + \mathop{NaCl}_{\left(Q\right)}

The white precipitate manganese hydroxide on reaction with lead dioxide and concentrated sulphuric acid gives purple coloured solution permanganate.

Mn(OH)2→Conc.H2SO4,heatPbO2(excess)MnO4−(purplesolution)Mn{\left(OH\right)}_{2}\mathop{\to}_{Conc . {H}_{2}{SO}_{4}, heat}^{{PbO}_{2}\left(excess\right)}{MnO}_{4}^{-}\left(purplesolution\right)

The sodium chloride gives Cl2{Cl}_{2} on reaction with MnO(OH)2,conc.H2SO4MnO{\left(OH\right)}_{2}, conc . {H}_{2}{SO}_{4}. The chlorine formed can oxidise iodide to iodine which gives blue colouration with starch paper.

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