JEE Main 20266 AprilEvening Shift
- Exam
- JEE Main
- Year
- 2026
- Date
- 6 April
- Shift
- Evening Shift
- Subject
- Chemistry
- Chapter
- d and f Block Elements
JEE Main 2026 · 6 April · Evening Shift · Chemistry · d and f Block Elements
The correct order of first (Δ_i H_1) and second (Δ_i H_2)...
The correct order of first and second ionisation enthalpy values of Cr and Mn are :
A. Cr Mn
B. Cr Mn
C. Mn Cr
D. Mn Cr
Choose the correct answer from the options given below :
A. Cr Mn
B. Cr Mn
C. Mn Cr
D. Mn Cr
Choose the correct answer from the options given below :
Options
- AA and B only
- BB and C only
- CA and D only
- DC and D only
Correct answer
B. B and C only
Step-by-step solution
The electronic configuration of Cr is and Mn is .
For the first ionization enthalpy, the electron is removed from the orbital. Mn has a fully filled configuration and a higher effective nuclear charge compared to Cr. Thus, the first ionization enthalpy of Mn is greater than that of Cr ( Mn Cr). This makes statement C correct.
After the first ionization, the electronic configurations become:
For the second ionization enthalpy, the electron is removed from the highly stable half-filled subshell in , whereas in , it is removed from the orbital. Removing an electron from a stable half-filled configuration requires significantly more energy. Thus, the second ionization enthalpy of Cr is greater than that of Mn ( Cr Mn). This makes statement B correct.
Therefore, the correct statements are B and C.
Answer: B and C only
For the first ionization enthalpy, the electron is removed from the orbital. Mn has a fully filled configuration and a higher effective nuclear charge compared to Cr. Thus, the first ionization enthalpy of Mn is greater than that of Cr ( Mn Cr). This makes statement C correct.
After the first ionization, the electronic configurations become:
For the second ionization enthalpy, the electron is removed from the highly stable half-filled subshell in , whereas in , it is removed from the orbital. Removing an electron from a stable half-filled configuration requires significantly more energy. Thus, the second ionization enthalpy of Cr is greater than that of Mn ( Cr Mn). This makes statement B correct.
Therefore, the correct statements are B and C.
Answer: B and C only