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JEE Main 20265 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
5 April
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2026 · 5 April · Evening Shift · Chemistry · d and f Block Elements

A paper dipped in a dil. H_2SO_4 solution of ' X ' upon treatment...

A paper dipped in a dil. H2SO4H_2SO_4 solution of 'XX' upon treatment with SO2SO_2 gas turns into green. The compound 'XX' is :

Options

  1. AKI-starch
  2. BKMnO4KMnO_4
  3. CPb(CH3COO)2Pb(CH_3COO)_2
  4. DK2Cr2O7K_2Cr_2O_7

Correct answer

D. K2Cr2O7K_2Cr_2O_7

Step-by-step solution

SO2SO_2 gas acts as a reducing agent. When a paper dipped in an acidified solution of potassium dichromate (K2Cr2O7K_2Cr_2O_7) is exposed to SO2SO_2 gas, the orange-colored dichromate ion (Cr2O72−Cr_2O_7^{2-}) is reduced to the green-colored chromium(III) ion (Cr3+Cr^{3+}).

The chemical reaction is:
K2Cr2O7+H2SO4+3SO2→K2SO4+Cr2(SO4)3+H2OK_2Cr_2O_7 + H_2SO_4 + 3SO_2 \rightarrow K_2SO_4 + Cr_2(SO_4)_3 + H_2O

The formation of chromium(III) sulfate, Cr2(SO4)3Cr_2(SO_4)_3, is responsible for the green color.

Thus, the compound 'XX' is K2Cr2O7K_2Cr_2O_7.

Answer: K2Cr2O7K_2Cr_2O_7
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