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JEE Main 20264 AprilEvening Shift
Exam
JEE Main
Year
2026
Date
4 April
Shift
Evening Shift
Subject
Chemistry
Chapter
d and f Block Elements

JEE Main 2026 · 4 April · Evening Shift · Chemistry · d and f Block Elements

Pairs of elements with the same number of electrons in their...

Pairs of elements with the same number of electrons in their respective 4f orbital are
[Atomic number. Eu-63, Gd-64, Dy-66, Ho-67, Tm-69, Yb-70, Lu-71, Hf-72]
A. (Eu and Gd)
B. (Dy and Ho)
C. (Yb and Hf)
D. (Lu and Tm)
Choose the correct answer from the options given below:

Options

  1. AB and C Only
  2. BA and B Only
  3. CA and D Only
  4. DA and C Only

Correct answer

D. A and C Only

Step-by-step solution

The electronic configurations of the given elements are:

Eu (63): [Xe] 4f76s24f^7 6s^2
Gd (64): [Xe] 4f75d16s24f^7 5d^1 6s^2
Dy (66): [Xe] 4f106s24f^{10} 6s^2
Ho (67): [Xe] 4f116s24f^{11} 6s^2
Tm (69): [Xe] 4f136s24f^{13} 6s^2
Yb (70): [Xe] 4f146s24f^{14} 6s^2
Lu (71): [Xe] 4f145d16s24f^{14} 5d^1 6s^2
Hf (72): [Xe] 4f145d26s24f^{14} 5d^2 6s^2

From the above configurations:
Eu and Gd both have 7 electrons in their 4f4f orbitals.
Yb and Hf both have 14 electrons in their 4f4f orbitals.
Dy and Ho have 10 and 11 electrons respectively in their 4f4f orbitals.
Lu and Tm have 14 and 13 electrons respectively in their 4f4f orbitals.

Thus, pairs A (Eu and Gd) and C (Yb and Hf) have the same number of electrons in their respective 4f4f orbitals.

Answer: A and C Only
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