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JEE Advanced 2017Paper 2
Exam
JEE Advanced
Year
2017
Paper
Paper 2
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Advanced 2017 · Paper 2 · Chemistry · p Block Elements (Group 13 & 14)

Among the following, the correct statement(s) is(are)

Among the following, the correct statement(s) is(are)Among the following, the correct statement(s) is(are)Among the following, the correct statement(s) is(are)Among the following, the correct statement(s) is(are)

Options

  1. AAl{\left(C{H}_{3}\right)}_{3} has the three-centre two-electron bonds in its dimeric structure
  2. BAlCl3AlC{l}_{3} has the three-centre two-electron bonds in its dimeric structure
  3. CBH3B{H}_{3} has the three-centre two-electron bonds in its dimeric structure
  4. DThe Lewis acidity of BCl3BC{l}_{3} is greater than that of AlCl3AlC{l}_{3}

Correct answer

A. Al{\left(C{H}_{3}\right)}_{3} has the three-centre two-electron bonds in its dimeric structure

Step-by-step solution

(i) Among the following, the correct statement(s) is(are)

(ii) Among the following, the correct statement(s) is(are)

(iii) Among the following, the correct statement(s) is(are)

(iv)  Lewis acidic strength decreases down the group. The decrease in acid strength occurs because as size increases, the attraction between the incoming electron pair and the nucleus weakens.

Hence Lewis acidic strength of BCl3BC{l}_{3} is more than AlCl3.AlC{l}_{3} .

 

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