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JEE Advanced 2016Paper 1
Exam
JEE Advanced
Year
2016
Paper
Paper 1
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Advanced 2016 · Paper 1 · Chemistry · p Block Elements (Group 13 & 14)

The crystalline form of borax has

The crystalline form of borax hasThe crystalline form of borax has

Options

  1. ATetra nuclear [B4O5(OH)4]2−{\left[{B}_{4}{O}_{5}{\left(OH\right)}_{4}\right]}^{2 -} unit
  2. BAll boron atoms in the same plane
  3. CEqual number of sp2s{p}^{2} and sp3s{p}^{3} hybridized boron atoms
  4. DOne terminal hydroxide per boron atom

Correct answer

A. Tetra nuclear [B4O5(OH)4]2−{\left[{B}_{4}{O}_{5}{\left(OH\right)}_{4}\right]}^{2 -} unit

Step-by-step solution

The crystalline form of borax has
(A) Having [B4O5(OH)4]2−{\left[{B}_{4}{O}_{5}{\left(OH\right)}_{4}\right]}^{2 -} tetra nuclear (boron) unit.
(B) All boron atoms not in same plane.
(C) Two boron are sp2s{p}^{2} hybridised and two boron are sp3s{p}^{3} hybridised.
(D) One terminal hydroxide per boron atom is present.
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