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JEE Advanced 2014Paper 1
Exam
JEE Advanced
Year
2014
Paper
Paper 1
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Advanced 2014 · Paper 1 · Chemistry · p Block Elements (Group 13 & 14)

The correct statement(s) for orthoboric acid is/are

The correct statement(s) for orthoboric acid is/areThe correct statement(s) for orthoboric acid is/are

Options

  1. AIt behaves as a weak acid in water due to self ionization.
  2. BAcidity of its aqueous solution increases upon addition of ethylene glycol.
  3. CIt has a three dimensional structure due to hydrogen bonding.
  4. DIt is a weak electrolyte in water.

Correct answer

B. Acidity of its aqueous solution increases upon addition of ethylene glycol.

Step-by-step solution

A] H3BO3{H}_{3}B{O}_{3} is a weak monobasic Lewis acid.
H3BO3+H−OH⇌B(OH)4−+H+…..(i){H}_{3}B{O}_{3} + H - OH ⇌ B{\left(OH\right)}_{4}^{-} + {H}^{+} \ldots . . ( i )
B] Equilibrium (i) is shifted in forward direction by the addition of syn-diols like ethylene glycol which forms a stable complex with B(OH)4−B{\left(OH\right)}_{4}^{-} .

The correct statement(s) for orthoboric acid is/are
C] It has a planar sheet like structure due to hydrogen bonding.
D] H3BO3{H}_{3}B{O}_{3} is a weak electrolyte in water.

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