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JEE Advanced 2006
Exam
JEE Advanced
Year
2006
Subject
Chemistry
Chapter
p Block Elements (Group 13 & 14)

JEE Advanced 2006 · Chemistry · p Block Elements (Group 13 & 14)

B(OH)_3+NaOH leftharpoons NaBO_2+Na[B(OH)_4]+H_2 O . How can this...

B(OH)3+NaOH⇌NaBO2+Na[B(OH)4]+H2O\mathrm{B}(\mathrm{OH})_3+\mathrm{NaOH} \rightleftharpoons \mathrm{NaBO}_2+\mathrm{Na}\left[\mathrm{B}(\mathrm{OH})_4\right]+\mathrm{H}_2 \mathrm{O}. How can this reaction is made to proceed in forward direction?B(OH)_3+NaOH leftharpoons NaBO_2+Na[B(OH)_4]+H_2 O . How can this reaction is made to proceed in forward direction?B(OH)_3+NaOH leftharpoons NaBO_2+Na[B(OH)_4]+H_2 O . How can this reaction is made to proceed in forward direction?B(OH)_3+NaOH leftharpoons NaBO_2+Na[B(OH)_4]+H_2 O . How can this reaction is made to proceed in forward direction?

Options

  1. AAddition of cis 1, 2 diol
  2. BAddition of borax
  3. CAddition of trans 1, 2 diol
  4. DAddition of Na2HPO4\mathrm{Na}_2 \mathrm{HPO}_4

Correct answer

A. Addition of cis 1, 2 diol

Step-by-step solution

B(OH)_3+NaOH leftharpoons NaBO_2+Na[B(OH)_4]+H_2 O . How can this reaction is made to proceed in forward direction?
This reaction is reversible reaction because sodium metaborate, Na+\mathrm{Na}^{+}\left[\mathrm{B}(\mathrm{OH})_4\right]^{-}formedbythereactionbetweenformed by the reaction between\mathrm{B}(\mathrm{OH})_3andand\mathrm{NaOH}getshydrolysedtoregenerategets hydrolysed to regenerate\mathrm{B}(\mathrm{OH})_3andand\mathrm{NaOH}<imgsrc="https://cdn−question−pool.getmarks.app/pyq/jeeadvanced/HTQ4yy4c1xOjkvE9BMrxfhp7VKkCLr5fdyJ0Wx66E.original.fullsize.png"><br>If,somequantityofpolyhydroxycompoundlikecis−1,3−diol,catechol,glyceroletc.isaddedtothereactionmixture.The<img src="https://cdn-question-pool.Quantrex.app/pyq/jee_advanced/HTQ4_yy4c1xOjkvE_9BMrxfhp7VKkCLr5fdyJ0Wx66E.original.fullsize.png"><br> If, some quantity of polyhydroxy compound like cis-1, 3-diol, catechol, glycerol etc. is added to the reaction mixture. The\mathrm{B}(\mathrm{OH})_3 combines with such polyhydroxy compound to give chelated complex compound. Due to complex compound formation, stability increases and due to higher stability of complex, reaction moves in forward direction.B(OH)_3+NaOH leftharpoons NaBO_2+Na[B(OH)_4]+H_2 O . How can this reaction is made to proceed in forward direction?
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