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JEE Advanced 2022Paper 2
Exam
JEE Advanced
Year
2022
Paper
Paper 2
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Advanced 2022 · Paper 2 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

The compound(s) which react(s) with NH _ 3 to give boron nitride...

The compound(s) which react(s) with NH3{NH}_{3} to give boron nitride (BN)\left(BN\right) is(are)

Options

  1. ABB
  2. BB2H6{B}_{2}{H}_{6}
  3. CB2O3{B}_{2}{O}_{3}
  4. DHBF4{HBF}_{4}

Correct answer

A. BB

Step-by-step solution

The compound(s) which react with NH3{NH}_{3} to form Boron nitride (BN)\left(BN\right) is/are:

(A) Amorphous B+NH3⟶TempreatureBN+H2B + {NH}_{3}\mathop{⟶}_{Tempreature}BN + {H}_{2}

(B) B2H6+NH3(excess)⟶HighTemp.(BN)x{B}_{2}{H}_{6} + \mathop{{NH}_{3}}_{\left(excess\right)}\overset{HighTemp .}{⟶}{\left(BN\right)}_{x}

(C) B2O3+2NH3⟶900°C2BN+3H2O{B}_{2}{O}_{3} + 2{NH}_{3}\overset{900 ° C}{⟶}2BN + 3{H}_{2}O

(D) HBF4+NH3⟶[NH4⊕][BF4⊖]{HBF}_{4} + {NH}_{3} ⟶ \left[{NH}_{4}^{⊕}\right]\left[{BF}_{4}^{⊖}\right]

Hence, (A,B,C) are correct

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