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JEE Advanced 2017Paper 1
Exam
JEE Advanced
Year
2017
Paper
Paper 1
Subject
Chemistry
Chapter
p Block Elements (Group 15, 16, 17 & 18)

JEE Advanced 2017 · Paper 1 · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

The correct statements about the oxoacids, HClO _ 4 andHClO are,

The correct statements about the oxoacids, HClO4andHClO{HClO}_{4}andHClO are,The correct statements about the oxoacids, HClO _ 4 andHClO are,The correct statements about the oxoacids, HClO _ 4 andHClO are,

Options

  1. Athe conjugate base of HClO4{HClO}_{4} is weaker base than HClOHClO.
  2. Bthe central atom in both HClO4{HClO}_{4} and HClOHClOis sp3{sp}^{3} hybridized.
  3. CHClO4{HClO}_{4} is formed in the reaction between Cl2andH2O{Cl}_{2}and{H}_{2}O.
  4. DHClO4{HClO}_{4} is more acidic than HClOHClObecause of the resonance stabilization of its anion.

Correct answer

A. the conjugate base of HClO4{HClO}_{4} is weaker base than HClOHClO.

Step-by-step solution

(i)  HClO4⇌H++ClO4−{HClO}_{4} ⇌ {H}^{+} + {ClO}_{4}^{-}

ClO4−{ClO}_{4}^{-}  is resonance stabilized anion.

HClO⇌H++ClO−HClO ⇌ {H}^{+} + {ClO}^{-}

∴HClO4∴ {HClO}_{4} is more acidic then HClO.HClO .

(ii)   Cl2+H2O→HClO+HCl{Cl}_{2} + {H}_{2}O \to HClO + HCl

(iii)  HClO4{HClO}_{4} The correct statements about the oxoacids, HClO _ 4 andHClO are,The central atom is sp3{sp}^{3} hybridised.

The correct statements about the oxoacids, HClO _ 4 andHClO are, The central atom is sp3{sp}^{3} hybridised.

(iv)  HClO4+H2O→H3O⊕+ClO4−{HClO}_{4} + {H}_{2}O \to {H}_{3}{O}^{⊕} + {ClO}_{4}^{-} since H2O{H}_{2}O is accepting H+{H}^{+} from HClO4{HClO}_{4} so H2O{H}_{2}O  is stronger base compare to ClO4−{ClO}_{4}^{-}.

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