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JEE Advanced 2014Paper 2
Exam
JEE Advanced
Year
2014
Paper
Paper 2
Subject
Chemistry
Chapter
Practical Chemistry

JEE Advanced 2014 · Paper 2 · Chemistry · Practical Chemistry

Paragraph: An aqueous solution of metal ion M 1 reacts separately...

Paragraph: An aqueous solution of metal ion M1\mathbf{M} 1 reacts separately with reagents Q\mathbf{Q} and R\mathbf{R} in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous solution of M2\mathbf{M} 2 on reaction with reagent S\mathbf{S} gives white precipitate which dissolves in excess of S\mathbf{S}. The reactions are summarized in the scheme given below: Paragraph: An aqueous solution of metal ion M 1 reacts separately with reagents Q and R in excess to give tetrahedral

Question: M1,Q\mathbf{M} 1, \mathbf{Q} and R\mathbf{R}, respectively are

Options

  1. AZn2+,KCNandHClZ{n}^{2 +}, KCNandHCl
  2. BNi2+,HClandKCNN{i}^{2 +}, HClandKCN
  3. CCd2+,KCNandHClC{d}^{2} + , KCNandHCl
  4. DCo2+,HClandKCNC{o}^{2 +}, HClandKCN

Correct answer

B. Ni2+,HClandKCNN{i}^{2 +}, HClandKCN

Step-by-step solution

Paragraph: An aqueous solution of metal ion M 1 reacts separately with reagents Q and R in excess to give tetrahedral
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