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Practical Chemistry — JEE Main & Advanced Chemistry PYQs

130 previous year questions from Practical Chemistry with answers and solutions. Numbered list, year tags, and one-tap solutions — built for serious JEE / NEET practice.

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1

Passage: Consider the following reaction sequence in which J , K , L and M are the major products. Given: Atomic mass (in amu): H : 1 , C : 12 , N : 14 , O : 16 , S : 32 , Br : 80

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2

Among Fe³⁺ , Pb²⁺ , Cu²⁺ and Mn²⁺ , identify the one that gets precipitated out while passing H₂S in presence of NH₄OH as group reagent. The highest possible oxidation state of the

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3

Among Fe²⁺, Fe³⁺, Cr²⁺ and Zn²⁺ , the ion that shows positive borax bead test and with highest ionisation enthalpy is:

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4

A salt with few drops of conc. HCl gives apple green colour in flame test. The group precipitate of the salt is dissolved in acetic acid and treated with K₂CrO₄ to give yellow prec

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5

A student has been given 0.314 g of an organic compound and asked to estimate Sulphur. During the experiment, the student has obtained 0.4813 g of barium sulphate. The percentage o

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6

In the Group analysis of cations, Ba ²⁺ ~ &~ Ca ²⁺ are precipitated respectively as

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7

Consider three metal chlorides x , y and z, where x is water soluble at room temperature, y is sparingly soluble in water at room temperature and z is soluble in hot water. x , y a

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8

By usual analysis, 1.00 g of compound ( X ) gave 1.79 g of magnesium pyrophosphate. The percentage of phosphorus in compound (X) is : (nearest integer) (Given, molar mass in g mol

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9

The correct match of the group reagents in List-I for precipitating the metal ion given in List-II from solutions, is List-I List-II (P) Passing H ₂ ~S in the presence of NH ₄ OH (

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10

When a salt is treated with sodium hydroxide solution it gives gas X . On passing gas X through reagent Y a brown coloured precipitate is formed. X and Y respectively, are

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11

Formation of Na ₄ [ Fe ( CN )₅ NOS ] , a purple coloured complex formed by addition of sodium nitroprusside in sodium carbonate extract of salt indicates the presence of :

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12

Choose the correct tests with respective observations. (A) ( CuSO ₄ ) (acidified with acetic acid) (+ K ₄ [ Fe ( CN )₆ ] ) Chocolate brown precipitate. (B) ( FeCl ₃+ K ₄ [ Fe ( CN

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13

Among the following cations, the number of cations which will give characteristic precipitate in their identification tests with K ₄ [ Fe ( CN )₆ ] is _____. Cu ²⁺, Fe ³⁺, Ba ²⁺, C

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14

Identify A , B and C in the given below reaction sequence A HNO ₃ ~Pb ( NO ₃ )₂ H ₂ SO ₄ B [ (2) Acetic acid (3) K ₂ CrO ₄ ] (1) Ammonium acetate

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15

Consider the following test for a group-IV cation. ( aligned & M ²⁺+ H ₂ ~S A (Black precipitate) + by product & A + aqua regia B + NOCl + S + H ₂ O & B + KNO ₂+ CH ₃ COOH C + by p

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16

Match List I with List II ( array |l|l|l|l| & List-I & & List-II & (Name of the test) & & (Reaction sequence involved) [M is metal] A. & Borax bead test & I. & MCO ₃ MO Co ( NO ₃ )

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17

During the detection of acidic radical present in a salt, a student gets a pale yellow precipitate soluble with difficulty in ( NH ₄ OH ) solution when sodium carbonate extract was

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18

Match List - I with List - II. ( array ll List - I & List - II Reaction & Type of redox reaction (A) Li & (I) 589.2 (B) Na & (II) 455.5 (C) Rb & (III) 670.8 (D) Cs & (IV) 780.0 arr

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19

Match List I with List II ( array |l|l|l|l| & List - I & & List - II & (Precipitating reagent and conditions) & & (Cation) A. & NH ₄ Cl + NH ₄ OH / ARKS & I. & Mn ²⁺ B. & NH ₄ OH +

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20

In a borax bead test under hot condition, a metal salt (one from the given) is heated at point B of the flame, resulted in green colour salt bead. The spin-only magnetic moment val

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21

In the precipitation of the iron group (III) in qualitative analysis, ammonium chloride is added before adding ammonium hydroxide to :

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22

The number of white coloured salts among the following is ....... A SrSO 4 B Mg NH 4 PO 4 C BaCrO 4 D Mn ( OH ) 2 E PbSO 4 F PbCrO 4 G AgBr H PbI 2 I CaC 2 O 4 J Fe ( OH ) 2 CH 3 C

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23

The compound that is white in color is

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24

Molar mass of the salt from NaBr , NaNO 3 , KI and CaF 2 which does not evolve coloured vapours on heating with concentrated H 2 SO 4 is ____ g mol – 1 , (Molar mass in g mol – 1 :

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25

Number of metal ions characterized by flame test among the following is _________. Sr 2 + , Ba 2 + , Ca 2 + , Cu 2 + , Zn 2 + , Co 2 + , Fe 2 +

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26

Given below are two statements: Statement-I: The gas liberated on warming a salt with dil H 2 SO 4 , turns a piece of paper dipped in lead acetate into black, it is a confirmatory

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27

The Lassiagne's extract is boiled with dil HNO 3 before testing for halogens because,

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28

On passing a gas, ' X ', through Nessler's reagent, a brown precipitate is obtained. The gas ' X ' is

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29

A reagent which gives brilliant red precipitate with Nickel ions in basic medium is

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30

Oxidation state of Fe(Iron) in complex formed in Brown ring test.

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31

In the wet tests for detection of various cations by precipitation, Ba 2 + cations are detected by obtaining precipitate of

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32

Formation of which complex, among the following, is not a confirmatory test of Pb 2 + ions

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33

Given below are two statements : Statement I : Upon heating a borax bead dipped in cupric sulphate in a luminous flame, the colour of the bead becomes green. Statement II : The gre

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34

In the wet tests for identification of various cations by precipitation, which transition element cation doesn't belong to group IV in qualitative inorganic analysis?

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35

A white precipitate was formed when BaCl 2 was added to water extract of an inorganic salt. Further, a gas ' X ' with characteristic odour was released when the formed whit

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36

Match List I with List II. List-I (Anion) List-II (gas evolved on reaction with dil. H 2 SO 4 ) (A) CO 3 2 - (I) Colourless gas which turns lead acetate paper black. (B) S 2 - (II)

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37

Which of the following is structure of a separating funnel?

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38

Which statement is not true with respect to nitrate ion test?

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39

In the flame test of a mixture of salts, a green flame with blue centre was observed. Which one of the following cations may be present?

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40

During the qualitative analysis of salt with cation y 2 + , addition of a reagent X to alkaline solution of the salt gives a bright red precipitate. The reagent X and the cation y

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41

A mixture of two salts is used to prepare a solution S , which gives the following results: White precipitate s only ← Room temperature Dilute NaOH ( aq ) S aq . solution of

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42

To an aqueous solution containing ions such as Al 3 + , Zn 2 + , Ca 2 + , Fe 3 + , Ni 2 + , Ba 2 + and Cu 2 + was added conc . HCl , followed by H 2 S . The total number of cations

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43

Match List-I with List-II List-I List-II Test/Reagents/Observation(s) Species detected (a) Lassaigne's Test (i) Carbon (b) Cu(II) oxide (ii) Sulphur (c) Silver nitrate (iii) N

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44

Given below are two statements: Statement I : Colourless cupric metaborate is reduced to cuprous metaborate in a luminous flame. Statement II : Cuprous metaborate is obtained by he

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45

A colorless aqueous solution contains nitrates of two metals, X and Y . When it was added to an aqueous solution of NaCl , a white precipitate was formed. This precipitate was foun

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46

The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20

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47

A red solid is insoluble in water. However, it becomes soluble if some K I is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fum

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48

Passing H 2 S in to a mixture of M n 2 + , N i 2 + , C u 2 + and H g 2 + ions in an acidified aqueous solution precipitates

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49

A solution of a metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless solution. Moreover, the solution of metal ion on treatment

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50

Gradual addition of potassium iodide solution to aqueous B i N O 3 3 solution initially produces a dark brown precipitate which dissolves in excess of KI to give a clear yellow sol

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51

On heating a mixture of N a C l , K 2 C r 2 O 7 and conc. H 2 S O 4 which of the following is formed ?

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52

Consider following reactions: The sum of molecular masses of gas A and B is ____________ u .

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53

The correct option(s) to distinguish nitrate salts of M n 2 + and C u 2 + taken separately is (are) (1) M n 2 + shows the characteristic green colour in the flame test (2) only C u

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54

Pick out the incorrect statement.

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55

Which salt on heating with conc. H 2 S O 4 gives violet vapours?

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56

Sodium fusion extract of an organic compound gives a blood red colouration with few drops of FeCl 3 solution. This indicates the presence of

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57

When phosphate radical react with ammonium molybdate, the colour of precipitate obtained is

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58

0.45 gm of an organic compound gave on combustion 0.792 gm of CO 2 and 0.324 gm of water. 0.24 gm of the same substance was Kjeldahlised and the ammonia liberated was absorbed in 5

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59

The correct match between item 'I' and item 'II' is Item I (Compound) Item II (Reagent) (1) Lysine (P) 1-naphthol (2) Furfural (Q) ninhydrin (3) Isopropyl alcohol (R) K M n O 4 (4)

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60

The green colour produced in the borax bead test of a chromium(III) salt is due to -

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61

An organic compound ‘A’ is oxidized with N a 2 O 2 followed by boiling with H N O 3 . The resultant solution is then treated with ammonium molybdate to yield a yellow p

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62

The correct option(s) to distinguish nitrate salts of M n 2 + a n d C u 2 + taken separately is(are)

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63

In the following reaction sequence in aqueous solution, the species X, Y and Z respectively, are S 2 O 3 2 − → Ag + X Clear Solution → Ag + Y White Precipitate → With time Z Black

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64

The reagent(s) that can selectively precipitate S 2 - from a mixture of S 2 - and S O 4 2 - in aqueous solution is (are)

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65

The pair(s) of ions where BOTH the ions are precipitated upon passing H 2 S gas in presence of dilute HCl, is (are)

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66

Paragraph: An aqueous solution of metal ion M 1 reacts separately with reagents Q and R in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution

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67

Paragraph: An aqueous solution of metal ion M 1 reacts separately with reagents Q and R in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution

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68

Paragraph: An aqueous solution of a mixture of two inorganic salts, when treated with dilute H C ?, gave a precipitate ( P ) and a filtrate ( Q ) . The precipitate P was found to d

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69

Upon treatment with ammoniacal H 2 S , the metal ion that precipitates as a sulphide is

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70

For the given aqueous reactions, which of the statement (s) is (are) true?

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71

Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction as shown in the given scheme.

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72

Which of the following halides react(s) with AgNO ₃( aq ) to give a precipitate that dissolves in Na ₂ ~S ₂ O ₃( aq ) ?

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73

A solution of a metal ion when treated with KI gives a red precipitate which dissolved in excess KI to give a colourless solution. Moreover, the solution of metal ion on treatment

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74

A solution when diluted with H ₂ O and boiled, it gives a white precipitate. On addition of excess NH ₄ Cl / NH ₄ OH , the volume of precipitate decreases leaving behind a white ge

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75

Brown ring test is used for the detection of which radical?

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76

Give the correct order of initials T or F for following statements. Use T if statement is true and F if it is false. (i) Cu + undergoes disproportionation to Cu and Cu 2 + in aqueo

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77

A red solid is insoluble in water. However, it becomes soluble if some K I is added to water. Heating the red solid in a test tube results in liberation of some violet coloured fum

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78

A mixture of two salts is not water soluble but dissolves completely in dilute HCI to form a colourless solution. The mixture could be:

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79

Passing H 2 S in to a mixture of M n 2 + , N i 2 + , C u 2 + and H g 2 + ions in an acidified aqueous solution precipitates

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80

X → KOH Y (gas turns red litmus blue) + Z → Zn + KOH Y (gas) . X → Δ gas (does not support combustion) Identify (X) to (Z):

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81

A chemistry student trying to detect the metallic ion in a salt, makes a paste on a clean platinum wire loop of the salt with concentrated H C l . When he takes a small amount of t

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82

In what order the reagents N a 2 S , N a C l and N a l are added to an aqueous solution containing Ag + , Cu + 2 and Ni + 2 ions in order to precipitate A g + first C u + 2 second

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83

Gradual addition of potassium iodide solution to aqueous B i N O 3 3 solution initially produces a dark brown precipitate which dissolves in excess of KI to give a clear yellow sol

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84

The correct option(s) to distinguish nitrate salts of M n 2 + and C u 2 + taken separately is (are) (1) M n 2 + shows the characteristic green colour in the flame test (2) only C u

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85

P b 2 + , C u 2 + , Z n 2 + and N i 2 + ions are present in a given acidic solution. On passing hydrogen sulphide gas through this solution, the available precipitate will contain

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86

Pick out the incorrect statement.

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87

In the following reaction sequence in aqueous solution, the species X, Y and Z respectively, are S 2 O 3 2 − → Ag + X Clear Solution → Ag + Y White Precipitate → With time Z Black

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88

How do you characterizes P b C r O 4 ?

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89

A solution of a metal ion when treated with KI gives a red precipitate which dissolves in excess KI to give a colourless solution. Moreover, the solution of metal ion on treatment

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90

Which of the following cations cannot be detected by the flame test?

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91

A chemistry student trying to detect the metallic ion in a salt, makes a paste on a clean platinum wire loop of the salt with concentrated H C l . When he takes a small amount of t

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92

A salt of NaX → MgCl 2 white ppt. on boiling. Thus, anion X is:

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93

Neutral ferric chloride is added to the aqueous solution of acetate. The blood red colour is obtained, it is due to the compound

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94

The metal that produces red violet colour in the non-luminous flame is

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95

Metal chloride A is soluble in hot water but insoluble in cold water. Select correct statement about A. Thus

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96

A doctor by mistake administers a Ba(NO 3 ) 2 solution to a patient for radiography investigations. Which of the following should be given as the best to prevent the absorption of

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97

Microcosmic salt bead test of salt X yields semi-translucent mass. Therefore it contains

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98

The colour of C u C r 2 O 7 solution in water is green because

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99

The carbonate of which of the following cation is insoluble in water?

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100

A solution of metal hydroxide (MOH) with copper sulphate and mixed tartarate of metal M with another metal M 1 of the same group, is used in the detection of -CHO group. Metal M an

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101

The borax bead is due to formation of

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102

Which of the following isomers will give white precipitate with B a C l 2 solution?

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103

Which metal will give blue colour metaborate in borax bead test?

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104

Which of the following acid radical will not produce a precipitate with A g N O 3 solution?

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105

Select pair(s) in which both produces same coloured ppt. with CrO ₄²⁻ ion

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106

X( ~s ) dil HCl Y [ Na ₃ ( Fe ( CNO )₃( NO ) ] . Purple solution Gas Y has been allowed to react with following Biack species in neutralacidic medium (A) FeCl ₃ (B) CuSO ₄ (C) BaCl

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107

Paragraph : Test (Q). A compound ' X ' was fused with Na metal and the extract gave a white precipitate with AgNO ₃ . The Lassaigne's extract gave red colouration with neutral FeCl

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108

Paragraph: Metal nitrate (A) on heating decomposes, leaving a solid residue (B) which goes into solution with dilute HCl . The solution of (B) gives a white precipitate (C) with am

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109

Paragraph: Metal nitrate (A) on heating decomposes, leaving a solid residue (B) which goes into solution with dilute HCl . The solution of (B) gives a white precipitate (C) with am

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110

Paragraph : Test (Q). A compound ' X ' was fused with Na metal and the extract gave a white precipitate with AgNO ₃ . The Lassaigne's extract gave red colouration with neutral FeCl

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111

An aqueous solution of a lead(II) salt is divided into two test tubes. Addition of potassium iodide to the first test tube produces a yellow precipitate 'X' which dissolves in boil

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112

An inorganic salt solution gives a white precipitate when treated with ( NH ₄)₂ CO ₃ in the presence of NH ₄ Cl and NH ₄ OH . The white precipitate is filtered and dissolved in dil

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113

An aqueous solution containing Pb²⁺ ions reacts with K₂CrO₄ to yield a yellow precipitate (A). When precipitate (A) is treated with hot concentrated NaOH , it dissolves to form a c

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114

An unknown transition metal salt X is subjected to the borax bead test. It forms a transparent blue bead when heated in an oxidizing flame and allowed to cool. When the same bead i

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115

An inorganic salt containing sulphur gives a characteristic purple colouration when its sodium carbonate extract is treated with sodium nitroprusside. The oxidation state of the ce

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116

An aqueous solution of an unknown metal salt is subjected to qualitative analysis. When H ₂ S gas is passed through the solution in the presence of dilute HCl , no precipitate is o

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117

When ammonia gas is passed through an alkaline solution of potassium tetraiodomercurate(II), a precipitate is formed. The colour and the chemical formula of this precipitate are re

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118

A Group IV transition metal cation M ²⁺ reacts with dimethylglyoxime in an ammoniacal medium to yield a brilliant red precipitate of a complex. The hybridization and the magnetic n

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119

Match List I with List II regarding the observations when aqueous solutions of the given metal cations are treated with potassium ferrocyanide, K ₄[ Fe ( CN )₆] . List I (Metal Cat

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120

A student is given an aqueous mixture containing Fe ³⁺ and Mg ²⁺ ions. Upon adding solid NH₄Cl followed by excess NH₄OH solution, a brown precipitate forms, but Mg ²⁺ remains in th

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