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JEE Advanced 2018Paper 1
Exam
JEE Advanced
Year
2018
Paper
Paper 1
Subject
Chemistry
Chapter
Solid State

JEE Advanced 2018 · Paper 1 · Chemistry · Solid State

Consider an ionic solid MX , with NaCl structure. Construct a new...

Consider an ionic solid MXMX, with NaClNaCl structure. Construct a new structure \left(Z\right),whoseunitcellisconstructedfromtheunitcellof, whose unit cell is constructed from the unit cell ofMX,followingthesequentialinstructionsgivenbelow.Neglectthechargebalance.<br/>, following the sequential instructions given below. Neglect the charge balance.<br />( i )Removealltheanions(X)Remove all the anions \left(X\right), except the central one.
(ii)( ii ) Replace all the face centered cations \left(M\right),byanions(X), by anions \left(X\right).
(iii)( iii ) Remove all the corner cations \left(M\right).<br/>.<br />( iv )Replacethecentralanion(X)Replace the central anion \left(X\right), with cation \left(M\right).<br/>Thevalueof(numberofanionsnumberofcations)inZ.<br />The value of \left(\dfrac{numberofanions}{numberofcations}\right) in Z is _____.

Correct answer

0

Step-by-step solution

X−⇒O.V{X}^{-} ⇒ O . V
M+⇒FCC{M}^{+} ⇒ FCC
M+{M}^{+} X−X ^ -
(i) 4 1
(ii) 4 – 3 3 + 1
(iii) 4 – 3 – 1 3 + 1
(iv) 1 3
Z=31=3Z = \dfrac{3}{1} = 3.
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