JEE Advanced 2015Paper 1
- Exam
- JEE Advanced
- Year
- 2015
- Paper
- Paper 1
- Subject
- Chemistry
- Chapter
- Solid State
JEE Advanced 2015 · Paper 1 · Chemistry · Solid State
If the unit cell of a mineral has cubic close packed (ccp) array of...
If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are
Options
- A
- B
- C
- D
Correct answer
A.
Step-by-step solution
In ccp, ions are 4.
Hence total negative charge = -8
Let ions be x, and ions be y.
Total positive charge = 3x + 2y
This relation is satisfied only by x = 2 and y = 1.
Hence number of
and number of
n = fraction of octahedral holes occupied by
and m = fraction of tetrahedral holes occupied by
Hence total negative charge = -8
Let ions be x, and ions be y.
Total positive charge = 3x + 2y
This relation is satisfied only by x = 2 and y = 1.
Hence number of
and number of
n = fraction of octahedral holes occupied by
and m = fraction of tetrahedral holes occupied by