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JEE Advanced 2015Paper 1
Exam
JEE Advanced
Year
2015
Paper
Paper 1
Subject
Chemistry
Chapter
Solid State

JEE Advanced 2015 · Paper 1 · Chemistry · Solid State

If the unit cell of a mineral has cubic close packed (ccp) array of...

If the unit cell of a mineral has cubic close packed (ccp) array of oxygen atoms with m fraction of octahedral holes occupied by aluminium ions and n fraction of tetrahedral holes occupied by magnesium ions, m and n, respectively, are

Options

  1. A12,18\dfrac{1}{2}, \dfrac{1}{8}
  2. B1,141, \dfrac{1}{4}
  3. C12,12\dfrac{1}{2}, \dfrac{1}{2}
  4. D14,18\dfrac{1}{4}, \dfrac{1}{8}

Correct answer

A. 12,18\dfrac{1}{2}, \dfrac{1}{8}

Step-by-step solution

In ccp, O2−{O}^{2 -} ions are 4.
Hence total negative charge = -8
Let Al3+A{l}^{3 +} ions be x, and Mg2+M{g}^{2 +} ions be y.
Total positive charge = 3x + 2y
⇒3x+2y=8⇒ 3x + 2y = 8
This relation is satisfied only by x = 2 and y = 1.
Hence number of Al3+=2A{l}^{3 +} = 2
and number of Mg2+=1M{g}^{2 +} = 1
⇒⇒ n = fraction of octahedral holes occupied by Al3+A{l}^{3 +}
=24=12= \dfrac{2}{4} = \dfrac{1}{2}
and m = fraction of tetrahedral holes occupied by Mg2+M{g}^{2 +}
=18= \dfrac{1}{8}
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