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JEE Advanced 2022Paper 1
Exam
JEE Advanced
Year
2022
Paper
Paper 1
Subject
Chemistry
Chapter
Some Basic Concepts of Chemistry

JEE Advanced 2022 · Paper 1 · Chemistry · Some Basic Concepts of Chemistry

The treatment of an aqueous solution of 3 . 74g of Cu ( NO _ 3 ) _...

The treatment of an aqueous solution of 3.74g3 . 74g of Cu(NO3)2Cu{\left({NO}_{3}\right)}_{2} with excess KIKI results in a brown solution along with the formation of a precipitate. Passing H2S{H}_{2}S through this brown solution gives another precipitate XX. The amount of XX (in gg) is____[Given: Atomic mass of H=1,N=14,O=16,S=32,K=39,Cu=63,I=127H = 1, N = 14, O = 16, S = 32, K = 39, Cu = 63, I = 127]

Correct answer

0

Step-by-step solution

Number of moles of Cu(NO3)2=3.74187=0.02Cu{\left({NO}_{3}\right)}_{2} = \dfrac{3 . 74}{187} = 0 . 02

2Cu(NO3)2+4KI→Cu2I2↓+I2+4KNO32Cu{\left({NO}_{3}\right)}_{2} + 4KI \to {Cu}_{2}{I}_{2} ↓ + {I}_{2} + 4{KNO}_{3}

Number of moles of Cu2l2{Cu}_{2}{l}_{2} precipitated =0.01= 0 . 01

I2(brownsolution)+H2S→S↓+2HI{I}_{2}\left(brownsolution\right) + {H}_{2}S \to S ↓ + 2HI

Number of moles of SS precipitated =0.01= 0 . 01

Mass of SS precipitates =(0.01×32)g=0.32g= \left(0 . 01 \times 32\right)g = 0 . 32g

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