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JEE Advanced 2023Paper 2
Exam
JEE Advanced
Year
2023
Paper
Paper 2
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Advanced 2023 · Paper 2 · Chemistry · Thermodynamics (C)

The entropy versus temperature plot for phases α and β at 1 bar...

The entropy versus temperature plot for phases α\alpha and β\beta at 11 bar pressure is given. STandS0{S}_{T} and {S}_{0} are entropies of the phases at temperatures Tand0KT and 0K, respectively.

The entropy versus temperature plot for phases α and β at 1 bar pressure is given. S _ T and S _ 0 are entropies of the

The transition temperature for α\alpha to β\beta phase change is 600K and Cp,β−Cp,α=1Jmol−1K−1{C}_{p, \beta} - {C}_{p, \alpha} = 1J{mol}^{- 1}{K}^{- 1}. Assume (Cp,β−Cp,α)\left({C}_{p, \beta} - {C}_{p, \alpha}\right) is independent of temperature in the range of 200to700K.Cp,αandCp,β200 to 700K . {C}_{p, \alpha} and {C}_{p, \beta} are heat capacities of αandβ\alpha and \beta phases, respectively.


The value of entropy change, Sβ−Sα{S}_{\beta} - {S}_{\alpha} (in Jmol−1K−1{Jmol}^{- 1}{K}^{- 1} ), at 300K300K is [Use: ln⁡2=0.69\ln 2 = 0 . 690. Given: Sβ−Sα=0{S}_{\beta} - {S}_{\alpha} = 0 at 0K0K ]

Correct answer

0

Step-by-step solution

S=S0+∫CpdTTS = {S}_{0} + ∫{C}_{p}\dfrac{d T}{T}

Sα=S0+∫[Cp]αdTT{S}_{\alpha} = {S}_{0} + {∫}_{}{\left[{C}_{p}\right]}_{\alpha}\dfrac{d T}{T}

Sβ=S0+∫[Cp]βdTT{S}_{\beta} = {S}_{0} + {∫}_{}{\left[{C}_{p}\right]}_{\beta}\dfrac{d T}{T}

Now,

Sβ−Sα=S0+∫[[Cp]β−[Cp]α]dTT{S}_{\beta} - {S}_{\alpha} = {S}_{0} + ∫ \left[{\left[{C}_{p}\right]}_{\beta} - {\left[{C}_{p}\right]}_{\alpha}\right]\dfrac{d T}{T}

Given [Cp]β−[Cp]α=1{\left[{C}_{p}\right]}_{\beta} - {\left[{C}_{p}\right]}_{\alpha} = 1

Sβ−Sα=ln⁡T+C{S}_{\beta} - {S}_{\alpha} = \ln T + C at any temperature of TT

[Sβ−Sα]T2−[Sβ−Sα]T1=ln⁡T2−ln⁡T1{\left[{S}_{\beta} - {S}_{\alpha}\right]}_{{T}_{2}} - {\left[{S}_{\beta} - {S}_{\alpha}\right]}_{{T}_{1}} = {\ln T}_{2} - {\ln T}_{1}

T2=600K,T1=300KandSβ−Sα=1at600K{T}_{2} = 600K, {T}_{1} = 300Kand{S}_{\beta} - {S}_{\alpha} = 1at600K

1−[Sβ−Sα]300=ln⁡600−ln⁡300⇒Sβ−Sα=1−0.69=0.311 - {\left[{S}_{\beta} - {S}_{\alpha}\right]}_{300} = \ln 600 - \ln 300 ⇒ {S}_{\beta} - {S}_{\alpha} = 1 - 0 . 69 = 0 . 31

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