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JEE Main 202427 JanuaryMorning Shift
Exam
JEE Main
Year
2024
Date
27 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Main 2024 · 27 January · Morning Shift · Chemistry · Thermodynamics (C)

If three moles of an ideal gas at 300K expand isothermally from 30...

If three moles of an ideal gas at 300K300K expand isothermally from 30dm330{dm}^{3} to 45dm345{dm}^{3} against a constant opposing pressure of 80kPa80kPa, then the amount of heat transferred is __________J.

Correct answer

0

Step-by-step solution

Given,

 V1=30dm3V2=45dm3P=80kPa{V}_{1} = 30{dm}^{3}{V}_{2} = 45{dm}^{3}P = 80kPa

Using, first law of thermodynamics,
ΔU=Q+W\Delta U = Q + W

QQ is the heat given or lost

ΔU\Delta U is the change in internal energy

WW is the work done

ΔU=0\Delta U = 0 : Process is isothermal

Q=−WQ = - W

W=−PextΔV:W = - {P}_{ext}\Delta V: Irreversible

W=−Pext(V2−V1)W = - {P}_{ext} ( {V}_{2} - {V}_{1} )

=−80×103(45−30)×10−3= - 80 \times {10}^{3} ( 45 - 30 ) \times {10}^{- 3}

=−1200J= - 1200J

Hence, the amount of heat transferred is 1200J1200J

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