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JEE Advanced 2014Paper 1
Exam
JEE Advanced
Year
2014
Paper
Paper 1
Subject
Chemistry
Chapter
Thermodynamics (C)

JEE Advanced 2014 · Paper 1 · Chemistry · Thermodynamics (C)

An ideal gas in a thermally insulated vessel at internal pressure =...

An ideal gas in a thermally insulated vessel at internal pressure = P1{P}_{1} , volume = V1{V}_{1} and absolute temperature = T1{T}_{1} expands irreversibly against zero external pressure, as shown in the diagram. The final internal pressure, volume and absolute temperature of the gas are P2{P}_{2} , V2{V}_{2} and T2{T}_{2} , respectively. For this expansion,

An ideal gas in a thermally insulated vessel at internal pressure = P _ 1 , volume = V _ 1 and absolute temperature = T

Options

  1. Aq=0q = 0
  2. BT2=T1{T}_{2} = {T}_{1}
  3. CP2V2=P1V1{P}_{2}{V}_{2} = {P}_{1}{V}_{1}
  4. DP2V2γ=P1V1γ{P}_{2}{V}_{2}^{\gamma} = {P}_{1}{V}_{1}^{\gamma}

Correct answer

A. q=0q = 0

Step-by-step solution

Since container is thermally insulated. So, q = 0, and it is a case of free expansion therefore W = 0 and
∆E=0∆ E = 0
So, T1=T2{T}_{1} = {T}_{2}
Also, P1V1=P2V2{P}_{1}{V}_{1} = {P}_{2}{V}_{2}
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