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JEE Main 202329 JanuaryMorning Shift
Exam
JEE Main
Year
2023
Date
29 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Alcohols Phenols and Ethers

JEE Main 2023 · 29 January · Morning Shift · Chemistry · Alcohols Phenols and Ethers

The increasing order of pK _ a for the following phenols is (A)...

The increasing order of pKa{pK}_{a} for the following phenols is

(A) 2,4-Dinitrophenol

(B) 4-Nitrophenol

(C) 2,4,5-Trimethylphenol

(D) Phenol

(E) 3-Chlorophenol

Choose the correct answer from the option given below :

The increasing order of pK _ a for the following phenols is (A) 2,4-Dinitrophenol (B) 4-Nitrophenol (C)

Options

  1. A(A), (E), (B), (D), (C)
  2. B(A), (B), (E), (D), (C)
  3. C(C), (D), (E), (B), (A)
  4. D(C), (E), (D), (B), (A)

Correct answer

B. (A), (B), (E), (D), (C)

Step-by-step solution

Order of acidity for following phenol is

The increasing order of pK _ a for the following phenols is (A) 2,4-Dinitrophenol (B) 4-Nitrophenol (C)

Increasing order of pKa means most acidic will be placed first.

−M- M groups at ortho and para position increases acidic strength in phenol. Hence, (A) is most acidic.

+M+ M, Hyperconjugation, +I+ I decreases Ka Value of 2,4,5-Trimethylphenol. Hence (C), is least acidity.

So, the order of pKa value is (A) < (B )< (E)< (D)< (C).

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