JEE Main 202329 JanuaryMorning Shift
- Exam
- JEE Main
- Year
- 2023
- Date
- 29 January
- Shift
- Morning Shift
- Subject
- Chemistry
- Chapter
- Alcohols Phenols and Ethers
JEE Main 2023 · 29 January · Morning Shift · Chemistry · Alcohols Phenols and Ethers
The increasing order of pK _ a for the following phenols is (A)...
The increasing order of for the following phenols is
(A) 2,4-Dinitrophenol
(B) 4-Nitrophenol
(C) 2,4,5-Trimethylphenol
(D) Phenol
(E) 3-Chlorophenol
Choose the correct answer from the option given below :
Options
- A(A), (E), (B), (D), (C)
- B(A), (B), (E), (D), (C)
- C(C), (D), (E), (B), (A)
- D(C), (E), (D), (B), (A)
Correct answer
B. (A), (B), (E), (D), (C)
Step-by-step solution
Order of acidity for following phenol is
Increasing order of pKa means most acidic will be placed first.
groups at ortho and para position increases acidic strength in phenol. Hence, (A) is most acidic.
, Hyperconjugation, decreases Ka Value of 2,4,5-Trimethylphenol. Hence (C), is least acidity.
So, the order of pKa value is (A) < (B )< (E)< (D)< (C).