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JEE Main 202622 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
22 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Biomolecules

JEE Main 2026 · 22 January · Morning Shift · Chemistry · Biomolecules

Given below are two statements: Statement I : Sucrose is...

Given below are two statements:
Statement I: Sucrose is dextrorotatory. However, sucrose upon hydrolysis gives a solution having mixture of products. This solution shows laevorotation.
Statement II: Hydrolysis of sucrose gives glucose and fructose. Since the laevorotation of glucose is more than the dextrorotation of fructose, the resulting solution becomes laevorotatory.
In the light of the above statements, choose the correct answer from the options given below

Options

  1. AStatement I is true but Statement II is false
  2. BStatement I is false but Statement II is true
  3. CBoth Statement I and Statement II are false
  4. DBoth Statement I and Statement II are true

Correct answer

A. Statement I is true but Statement II is false

Step-by-step solution

Sucrose is dextrorotatory with a specific rotation of +66.5∘+66.5^{\circ}.
Upon hydrolysis, sucrose breaks down into an equimolar mixture of D-(+)-glucose and D-(-)-fructose.
The specific rotation of D-(+)-glucose is +52.5∘+52.5^{\circ} (dextrorotatory).
The specific rotation of D-(-)-fructose is −92.4∘-92.4^{\circ} (laevorotatory).
Since the magnitude of laevorotation of fructose (92.4∘92.4^{\circ}) is greater than the magnitude of dextrorotation of glucose (52.5∘52.5^{\circ}), the resulting mixture is laevorotatory. This process is called inversion of sugar.
Statement I is true because sucrose is dextrorotatory and its hydrolysis product is laevorotatory.
Statement II is false because it incorrectly claims that glucose is laevorotatory and fructose is dextrorotatory, and that the laevorotation of glucose is more than the dextrorotation of fructose. In reality, glucose is dextrorotatory and fructose is laevorotatory.
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