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JEE Main202229 Jun 2022Morning ShiftChemistryCarboxylic Acid DerivativesActual

Given below are two statements : Statement I : The esterification of carboxylic acid with an alcohol is a nucleophilic acyl substitution. Statement II : Electron withdrawing groups in the carboxylic acid will increase the rate of esterification reaction. Choose the most appropriate option

Options

  1. AStatement I is correct but Statement II is incorrect.
  2. BBoth Statement I and Statement II are incorrect.
  3. CBoth Statement I and Statement II are correct.
  4. DStatement I is incorrect but Statement II is correct.

Correct answer

C. Both Statement I and Statement II are correct.

Step-by-step solution

In the above reaction OH group is replaced by OR group. Hence, nucleophilic substitution reaction is involved. Electron withdrawing groups increases the stability of R C ⊕ OH 2 , hence, rate of reaction increases.

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