JEE Main202227 Jun 2022Evening ShiftChemistryCarboxylic Acid DerivativesActual
Decarboxylation of all six possible forms of diaminobenzoic acids C 6 H 3 NH 2 2 COOH yields three products A , B and C . Three acids give a product ' A ', two acids gives a product ' B ' and one acid give a product ' C '. The melting point of product ' C ' is
Options
- A63   ° C
- B90   ° C
- C104   ° C
- D142   ° C
Correct answer
D. 142   ° C
Step-by-step solution
C is a para isomer. The melting point of para-isomer is comparatively higher than the corresponding ortho and meta-isomers , because of more symmetrical nature; it fits into crystal lattice more readily and so, close packing of molecules in crystal lattice increases the intermolecular force of attraction between molecules. Hence C has highest melting point that is 142   ° C