Quantrex Quantrex AcademyJEE · NEET · NDA PYQs with solutions Open app
JEE Main 202227 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
27 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Main 2022 · 27 June · Evening Shift · Chemistry · Carboxylic Acid Derivatives

Decarboxylation of all six possible forms of diaminobenzoic acids C...

Decarboxylation of all six possible forms of diaminobenzoic acids C6H3( NH 2){C}_{6}{H}_{3}{\left({\text{ NH }}_{2}\right)}_{2}COOHyieldsthreeproductsyields three productsA, BandandC.Threeacidsgiveaproduct′. Three acids give a product 'A′,twoacidsgivesaproduct′', two acids gives a product 'B′andoneacidgiveaproduct′' and one acid give a product 'C′.Themeltingpointofproduct′'. The melting point of product 'C' isDecarboxylation of all six possible forms of diaminobenzoic acids C _ 6 H _ 3 ( NH _ 2 ) _ 2 COOH yields three productsDecarboxylation of all six possible forms of diaminobenzoic acids C _ 6 H _ 3 ( NH _ 2 ) _ 2 COOH yields three productsDecarboxylation of all six possible forms of diaminobenzoic acids C _ 6 H _ 3 ( NH _ 2 ) _ 2 COOH yields three products

Options

  1. A63°C63 ° C
  2. B90°C90 ° C
  3. C104°C104 ° C
  4. D142°C142 ° C

Correct answer

D. 142°C142 ° C

Step-by-step solution

Decarboxylation of all six possible forms of diaminobenzoic acids C _ 6 H _ 3 ( NH _ 2 ) _ 2 COOH yields three products

Decarboxylation of all six possible forms of diaminobenzoic acids C _ 6 H _ 3 ( NH _ 2 ) _ 2 COOH yields three products

Decarboxylation of all six possible forms of diaminobenzoic acids C _ 6 H _ 3 ( NH _ 2 ) _ 2 COOH yields three productsC is a para isomer.

The melting point of para-isomer is comparatively higher than the corresponding ortho and meta-isomers , because of more symmetrical nature; it fits into crystal lattice more readily and so, close packing of molecules in crystal lattice increases the intermolecular force of attraction between molecules.

Hence (C)\left(C\right) has highest melting point that is 142°C142 ° C

Practice Carboxylic Acid Derivatives on Quantrex Academy →

More from Carboxylic Acid Derivatives

The sum of total number of carbonyl groups ( >C=O ) present in the major products X and Y… JEE Advanced 2026Complete the following reaction sequence and give the name of major product 'P'.… JEE Main 2026The descending order of acidity among the following compounds is: A. Phenol B. 4… JEE Main 2026The correct order of acidic strength of the major products formed in the given reactions… JEE Main 2026Monocyclic compounds P, Q, R and S are the major products formed in the reaction… JEE Advanced 2025The correct reaction/reaction sequence that would produce a dicarboxylic acid as the… JEE Advanced 2025Mixture of 1 g each of chlorobenzene, aniline and benzoic acid is dissolved in 50 mL… JEE Main 2025Which of the following compounds is least likely to give effervescence of CO_2 in… JEE Main 2025 Full Carboxylic Acid Derivatives list All JEE Main PYQs