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JEE Main202227 Jun 2022Evening ShiftChemistryCarboxylic Acid DerivativesActual

Decarboxylation of all six possible forms of diaminobenzoic acids C 6 H 3 NH 2 2 COOH yields three products A , B and C . Three acids give a product ' A ', two acids gives a product ' B ' and one acid give a product ' C '. The melting point of product ' C ' is

Options

  1. A63   ° C
  2. B90   ° C
  3. C104   ° C
  4. D142   ° C

Correct answer

D. 142   ° C

Step-by-step solution

C is a para isomer. The melting point of para-isomer is comparatively higher than the corresponding ortho and meta-isomers , because of more symmetrical nature; it fits into crystal lattice more readily and so, close packing of molecules in crystal lattice increases the intermolecular force of attraction between molecules. Hence C has highest melting point that is 142   ° C

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