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JEE Main 202226 JuneEvening Shift
Exam
JEE Main
Year
2022
Date
26 June
Shift
Evening Shift
Subject
Chemistry
Chapter
Carboxylic Acid Derivatives

JEE Main 2022 · 26 June · Evening Shift · Chemistry · Carboxylic Acid Derivatives

The reagent, from the following, which converts benzoic acid to...

The reagent, from the following, which converts benzoic acid to benzaldehyde in one step is

The reagent, from the following, which converts benzoic acid to benzaldehyde in one step is

Options

  1. ALiAlH4{LiAlH}_{4}
  2. BKMnO4{KMnO}_{4}
  3. CMnOMnO
  4. DNaBH4{NaBH}_{4}

Correct answer

C. MnOMnO

Step-by-step solution

When benzoic acid is heated with formic acid in presence of MnoMno, benzaldehyde is obtained.

The reaction is given below, along with benzaldehyde, carbondioxide and water are also obtained.

C6H5COOH+HCOOH→HeatMnOC6H5CHO+CO2+H2O{C}_{6}{H}_{5}COOH + HCOOH\mathop{\to}_{Heat}^{MnO}{C}_{6}{H}_{5}CHO + {CO}_{2} + {H}_{2}O

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