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JEE Main 202622 JanuaryMorning Shift
Exam
JEE Main
Year
2026
Date
22 January
Shift
Morning Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2026 · 22 January · Morning Shift · Chemistry · Chemical Bonding and Molecular Structure

Two p-block elements X and Y form fluorides of the type EF_ 3 . The...

Two p-block elements X and Y form fluorides of the type EF3\mathrm{EF}_{3}. The fluoride compound XF3\mathrm{XF}_{3} is a Lewis acid and YF3\mathrm{YF}_{3} is a Lewis base. The hybridizations of the central atoms of XF3\mathrm{XF}_{3} and YF3\mathrm{YF}_{3} respectively are

Options

  1. Asp2\mathrm{sp}^{2} and sp3\mathrm{sp}^{3}
  2. BBoth sp3\mathrm{sp}^{3}
  3. Csp3\mathrm{sp}^{3} and sp2\mathrm{sp}^{2}
  4. DBoth sp2\mathrm{sp}^{2}

Correct answer

A. sp2\mathrm{sp}^{2} and sp3\mathrm{sp}^{3}

Step-by-step solution

XF₃ is a Lewis acid, indicating the central atom X lacks a complete octet and can accept electron pairs. This is characteristic of Boron (B).
Boron in BF₃:
Valence electrons: 3
Steric number: 3 (three B-F bonds, no lone pairs)
Geometry: Trigonal planar
Hybridization: sp²
YF₃ is a Lewis base, indicating the central atom Y has lone pair(s) available to donate. This is characteristic of Nitrogen (N).
Nitrogen in NF₃:
Valence electrons: 5
Steric number: 4 (three N-F bonds + one lone pair)
Geometry: Trigonal pyramidal
Hybridization: sp³
Therefore, the hybridizations are sp² for XF₃ (Boron) and sp³ for YF₃ (Nitrogen).
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