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JEE Main202621 January 2026Evening ShiftChemistryChemical Bonding and Molecular StructureActual

The correct increasing order of C-H(A), C-O(B), C=O(C) and C N(D) bonds in terms of covalent bond length is:

Options

  1. AD < C < A < B
  2. BA < D < C < B
  3. CD < C < B < A
  4. DA < B < C < D

Correct answer

B. A < D < C < B

Step-by-step solution

Bond lengths depend on bond multiplicity and atomic sizes. C-H (single) ≈ 1.09 Å, C-O (single) ≈ 1.43 Å, C=O (double) ≈ 1.23 Å, C≡N (triple) ≈ 1.16 Å. Triple bonds are shorter than double bonds, which are shorter than single bonds. For single bonds, C-O is longer due to lower electronegativity difference compared to C-H. Increasing order of bond length: C-H (A) < C N (D) < C = O (C) < C-O (B) , giving A < D < C < B.

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