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JEE Main 202430 JanuaryEvening Shift
Exam
JEE Main
Year
2024
Date
30 January
Shift
Evening Shift
Subject
Chemistry
Chapter
Chemical Bonding and Molecular Structure

JEE Main 2024 · 30 January · Evening Shift · Chemistry · Chemical Bonding and Molecular Structure

Given below are two statements: One is labelled as Assertion A and...

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : H2Te{H}_{2}Te is more acidic than H2S{H}_{2}S.

Reason R: Bond dissociation enthalpy of H2Te{H}_{2}Te is lower than H2S{H}_{2}S.
In the light of the above statements. Choose the most appropriate from the options given below.

Options

  1. ABoth A and R are true but R is NOT the correct explanation of A.
  2. BBoth A and R are true and R is the correct explanation of A.
  3. CA is false but R is true.
  4. DA is true but R is false.

Correct answer

B. Both A and R are true and R is the correct explanation of A.

Step-by-step solution

Bond enthalpy, also referred to as bond energy or bond dissociation energy, is the energy required to break a particular covalent bond in one mole of molecule in a gaseous state.

The bond dissociation enthalpy of H2Te{H}_{2}Te is lower than that of H2S{H}_{2}S.

As a result, less energy is required to break the H2Te{H}_{2}Te bond, releasing [H]+ iseasier,andtheacidityof{\left[H\right]}^{+} is easier, and the acidity of{H}_{2}Teisgreater.</p><p>is greater.</p><p>{H}_{2}S, on the other hand, has a high bond dissociation energy and so has lower acidity.

Hence, Both A and R are true and R is the correct explanation of A.

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